• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

铁基金属有机框架材料活化过硫酸盐去除废水中有机污染物的研究进展

Progress in the Elimination of Organic Contaminants in Wastewater by Activation Persulfate over Iron-Based Metal-Organic Frameworks.

作者信息

Zhi Keke, Xu Jiajun, Li Shi, Luo Lingjie, Liu Dong, Li Zhe, Guo Lianghui, Hou Junwei

机构信息

Department of Engineering, China University of Petroleum-Beijing at Karamay, Karamay 834000, China.

State Key Laboratory, Heavy Oil Processing-Karamay Branch, Karamay 834000, China.

出版信息

Nanomaterials (Basel). 2024 Mar 5;14(5):473. doi: 10.3390/nano14050473.

DOI:10.3390/nano14050473
PMID:38470802
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10935196/
Abstract

The release of organic contaminants has grown to be a major environmental concern and a threat to the ecology of water bodies. Persulfate-based Advanced Oxidation Technology (PAOT) is effective at eliminating hazardous pollutants and has an extensive spectrum of applications. Iron-based metal-organic frameworks (Fe-MOFs) and their derivatives have exhibited great advantages in activating persulfate for wastewater treatment. In this article, we provide a comprehensive review of recent research progress on the significant potential of Fe-MOFs for removing antibiotics, organic dyes, phenols, and other contaminants from aqueous environments. Firstly, multiple approaches for preparing Fe-MOFs, including the MIL and ZIF series were introduced. Subsequently, removal performance of pollutants such as antibiotics of sulfonamides and tetracyclines (TC), organic dyes of rhodamine B (RhB) and acid orange 7 (AO7), phenols of phenol and bisphenol A (BPA) by various Fe-MOFs was compared. Finally, different degradation mechanisms, encompassing free radical degradation pathways and non-free radical degradation pathways were elucidated. This review explores the synthesis methods of Fe-MOFs and their application in removing organic pollutants from water bodies, providing insights for further refining the preparation of Fe-MOFs.

摘要

有机污染物的排放已成为一个主要的环境问题，并对水体生态构成威胁。基于过硫酸盐的高级氧化技术（PAOT）在消除有害污染物方面很有效，且具有广泛的应用范围。铁基金属有机框架材料（Fe-MOFs）及其衍生物在活化过硫酸盐用于废水处理方面展现出巨大优势。在本文中，我们全面综述了近期关于Fe-MOFs从水环境中去除抗生素、有机染料、酚类及其他污染物的巨大潜力的研究进展。首先，介绍了多种制备Fe-MOFs的方法，包括MIL和ZIF系列。随后，比较了各种Fe-MOFs对磺胺类和四环素类（TC）抗生素、罗丹明B（RhB）和酸性橙7（AO7）等有机染料、苯酚和双酚A（BPA）等酚类污染物的去除性能。最后，阐明了不同的降解机制，包括自由基降解途径和非自由基降解途径。本综述探讨了Fe-MOFs的合成方法及其在去除水体中有机污染物方面的应用，为进一步优化Fe-MOFs的制备提供了见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/0c33e4a64bc5/nanomaterials-14-00473-g024.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/f1dbf357ca10/nanomaterials-14-00473-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/016508736177/nanomaterials-14-00473-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/1c7116911d5f/nanomaterials-14-00473-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/40a79d491219/nanomaterials-14-00473-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/9a561fedf014/nanomaterials-14-00473-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/66aa70281e09/nanomaterials-14-00473-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/cfc8485696c4/nanomaterials-14-00473-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/5007b9f6ba47/nanomaterials-14-00473-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/6d88387b604d/nanomaterials-14-00473-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/3b48b4e68a0c/nanomaterials-14-00473-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/27cbb370f98c/nanomaterials-14-00473-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/74b07ab2b2b8/nanomaterials-14-00473-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/d39bc395a4fc/nanomaterials-14-00473-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/ef0ad31f737a/nanomaterials-14-00473-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/799a62d6e89f/nanomaterials-14-00473-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/f881d4ad4b0d/nanomaterials-14-00473-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/a4d2ef232e6e/nanomaterials-14-00473-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/4124f3e5f5fc/nanomaterials-14-00473-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/048ae60279ae/nanomaterials-14-00473-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/415146abc1fb/nanomaterials-14-00473-g020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/8cdf5ed8fd26/nanomaterials-14-00473-g021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/207ed268582f/nanomaterials-14-00473-g022.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/b9c705768cab/nanomaterials-14-00473-g023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/0c33e4a64bc5/nanomaterials-14-00473-g024.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/f1dbf357ca10/nanomaterials-14-00473-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/016508736177/nanomaterials-14-00473-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/1c7116911d5f/nanomaterials-14-00473-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/40a79d491219/nanomaterials-14-00473-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/9a561fedf014/nanomaterials-14-00473-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/66aa70281e09/nanomaterials-14-00473-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/cfc8485696c4/nanomaterials-14-00473-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/5007b9f6ba47/nanomaterials-14-00473-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/6d88387b604d/nanomaterials-14-00473-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/3b48b4e68a0c/nanomaterials-14-00473-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/27cbb370f98c/nanomaterials-14-00473-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/74b07ab2b2b8/nanomaterials-14-00473-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/d39bc395a4fc/nanomaterials-14-00473-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/ef0ad31f737a/nanomaterials-14-00473-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/799a62d6e89f/nanomaterials-14-00473-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/f881d4ad4b0d/nanomaterials-14-00473-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/a4d2ef232e6e/nanomaterials-14-00473-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/4124f3e5f5fc/nanomaterials-14-00473-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/048ae60279ae/nanomaterials-14-00473-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/415146abc1fb/nanomaterials-14-00473-g020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/8cdf5ed8fd26/nanomaterials-14-00473-g021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/207ed268582f/nanomaterials-14-00473-g022.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/b9c705768cab/nanomaterials-14-00473-g023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6652/10935196/0c33e4a64bc5/nanomaterials-14-00473-g024.jpg

相似文献

1
Progress in the Elimination of Organic Contaminants in Wastewater by Activation Persulfate over Iron-Based Metal-Organic Frameworks.铁基金属有机框架材料活化过硫酸盐去除废水中有机污染物的研究进展
Nanomaterials (Basel). 2024 Mar 5;14(5):473. doi: 10.3390/nano14050473.
2
Enhanced photocatalysis using metal-organic framework MIL-101(Fe) for organophosphate degradation in water.使用金属有机骨架 MIL-101(Fe) 增强光催化作用，在水中降解有机磷酸酯。
Environ Sci Pollut Res Int. 2019 Aug;26(24):24720-24732. doi: 10.1007/s11356-019-05649-2. Epub 2019 Jun 25.
3
Insights into High-Performance and Selective Elimination of Cationic Dye from Multicomponent Systems by Using Fe-Based Metal-Organic Frameworks.利用铁基金属有机框架对多组分体系中阳离子染料进行高效选择性去除的研究
Langmuir. 2022 Aug 2;38(30):9400-9409. doi: 10.1021/acs.langmuir.2c01354. Epub 2022 Jul 21.
4
Controllable synthesis of FeMn bimetallic ferrocene-based metal-organic frameworks to boost the catalytic efficiency for removal of organic pollutants.可控合成 FeMn 双金属二茂铁基金属有机骨架以提高去除有机污染物的催化效率。
Environ Sci Pollut Res Int. 2023 Feb;30(7):17449-17458. doi: 10.1007/s11356-022-23315-y. Epub 2022 Oct 4.
5
Ferrous metal-organic frameworks with strong electron-donating properties for persulfate activation to effectively degrade aqueous sulfamethoxazole.具有强给电子性质的亚铁金属有机框架用于过硫酸盐活化以有效降解水中的磺胺甲恶唑。
Chem Eng J. 2020 Aug 15;394. doi: 10.1016/j.cej.2020.125044. Epub 2020 Apr 11.
6
Advances and challenges in the removal of organic pollutants via sulfate radical-based advanced oxidation processes by Fe-based metal-organic frameworks: A review.铁基金属有机框架材料通过硫酸根自由基高级氧化过程去除有机污染物的研究进展与挑战：综述
Sci Total Environ. 2024 May 20;926:171885. doi: 10.1016/j.scitotenv.2024.171885. Epub 2024 Mar 26.
7
Ferrous metal-organic frameworks with stronger coordinatively unsaturated metal sites for persulfate activation to effectively degrade dibutyl phthalate in wastewater.具有更强配位不饱和金属位点的亚铁金属有机骨架用于过硫酸盐活化，以有效降解废水中的邻苯二甲酸二丁酯。
J Hazard Mater. 2019 Sep 5;377:163-171. doi: 10.1016/j.jhazmat.2019.05.081. Epub 2019 May 28.
8
Applications of water-stable metal-organic frameworks in the removal of water pollutants: A review.水稳定金属有机骨架在去除水中污染物中的应用：综述。
Environ Pollut. 2021 Dec 15;291:118076. doi: 10.1016/j.envpol.2021.118076. Epub 2021 Sep 2.
9
One-pot solvothermal synthesis of Cu-Fe-MOF for efficiently activating peroxymonosulfate to degrade organic pollutants in water:Effect of electron shuttle.一锅溶剂热法合成用于高效活化过一硫酸盐降解水中有机污染物的铜铁金属有机框架：电子穿梭体的影响
Chemosphere. 2024 Mar;352:141333. doi: 10.1016/j.chemosphere.2024.141333. Epub 2024 Feb 7.
10
Hydrogen sulfite promoted the activation of persulfate by μM Fe for bisphenol A degradation.亚硫酸氢盐促进了微摩尔级铁对过硫酸盐的活化以降解双酚A。
Environ Sci Pollut Res Int. 2022 Dec;29(56):85185-85201. doi: 10.1007/s11356-022-21801-x. Epub 2022 Jul 6.

引用本文的文献

1
Synthesis and characterization of MIL-88 A(Fe)/C composite for treatment of dairy factory's wastewater by enhanced electro-Fenton method.用于强化电芬顿法处理乳制品厂废水的MIL-88 A(Fe)/C复合材料的合成与表征
Sci Rep. 2025 Mar 12;15(1):8503. doi: 10.1038/s41598-025-92765-4.

本文引用的文献

1
One-pot solvothermal synthesis of Cu-Fe-MOF for efficiently activating peroxymonosulfate to degrade organic pollutants in water:Effect of electron shuttle.一锅溶剂热法合成用于高效活化过一硫酸盐降解水中有机污染物的铜铁金属有机框架：电子穿梭体的影响
Chemosphere. 2024 Mar;352:141333. doi: 10.1016/j.chemosphere.2024.141333. Epub 2024 Feb 7.
2
Nitrogen-doped Zn/Fe@PCN derived from metal-organic frameworks activating persulfate to efficiently degrade rhodamine B.氮掺杂的 Zn/Fe@PCN 由金属有机骨架激活过硫酸盐高效降解罗丹明 B。
Environ Sci Pollut Res Int. 2024 Jan;31(2):2228-2242. doi: 10.1007/s11356-023-31174-4. Epub 2023 Dec 6.
3
Synthesis of pH responsive malononitrile functionalized metal organic framework MIL-100(Fe) for efficient adsorption of uranium U(VI) from real-life alkaline leach liquor.
pH 响应型丙二腈功能化金属有机骨架 MIL-100(Fe)的合成及其从实际碱性浸出液中高效吸附铀(VI)的性能。
Chemosphere. 2024 Jan;348:140780. doi: 10.1016/j.chemosphere.2023.140780. Epub 2023 Nov 23.
4
Disease diagnosis and application analysis of molecularly imprinted polymers (MIPs) in saliva detection.分子印迹聚合物（MIPs）在唾液检测中的疾病诊断及应用分析。
Talanta. 2024 Mar 1;269:125394. doi: 10.1016/j.talanta.2023.125394. Epub 2023 Nov 6.
5
Novel conjugated microporous polymers for efficient tetracycline adsorption: insights from theoretical investigations.新型共轭微孔聚合物用于高效四环素吸附：理论研究的见解。
J Mol Graph Model. 2024 Jan;126:108655. doi: 10.1016/j.jmgm.2023.108655. Epub 2023 Oct 24.
6
CuFeS supported on dendritic mesoporous silica-titania for persulfate-assisted degradation of sulfamethoxazole under visible light.负载于树枝状介孔二氧化硅-二氧化钛上的CuFeS用于可见光下过硫酸盐辅助降解磺胺甲恶唑
J Colloid Interface Sci. 2024 Jan 15;654(Pt A):660-676. doi: 10.1016/j.jcis.2023.10.077. Epub 2023 Oct 17.
7
Enzymatic construction Au NPs-rGO based MIP electrochemical sensor for adulteration detection of bovine-derived allergen in camel milk.基于酶构建的 Au NPs-rGO 分子印迹电化学传感器用于骆驼奶中牛源性过敏原掺假检测。
Food Chem. 2024 Mar 15;436:137638. doi: 10.1016/j.foodchem.2023.137638. Epub 2023 Sep 29.
8
Heterostructure particles enable omnidispersible in water and oil towards organic dye recycle.异质结构颗粒能够在水和油中实现对有机染料回收的全向分散。
Nat Commun. 2023 Sep 18;14(1):5779. doi: 10.1038/s41467-023-41053-8.
9
Synthesis & characterization of novel MIP with RAFT polymerization of (2-hydroxy ethyl methacrylate)/chitosan as a nanocarrier for drug delivery applications.以甲基丙烯酸 2-羟乙酯/壳聚糖为纳米载体用于药物递送应用的新型分子印迹聚合物的可逆加成-断裂链转移聚合合成与表征
Int J Biol Macromol. 2023 Oct 1;250:126052. doi: 10.1016/j.ijbiomac.2023.126052. Epub 2023 Jul 28.
10
Non-Radical Activation of Peracetic Acid by Powdered Activated Carbon for the Degradation of Sulfamethoxazole.过碳酸钠非自由基活化粉末活性炭降解磺胺甲恶唑。
Environ Sci Technol. 2023 Jul 18;57(28):10478-10488. doi: 10.1021/acs.est.3c03370. Epub 2023 Jun 30.