Krzak Anna, Nowak Agnieszka J, Heljak Marcin, Antonowicz Jerzy, Garg Tushar, Sumption Michael
Scientific and Didactic Laboratory of Nanotechnology and Materials Technologies, Silesian University of Technology, 44-100 Gliwice, Poland.
Biomaterials Group, Materials Design Division, Faculty of Materials Science and Engineering, Warsaw University of Technology, 00-637 Warsaw, Poland.
Polymers (Basel). 2024 Feb 23;16(5):606. doi: 10.3390/polym16050606.
It is commonly acknowledged that polymer composites in service are often subjected to not only intricate mechanical loads but also harsh environmental conditions. The mechanical and thermal properties of five particular composites are explored here. The composites are composed of laminates of glass cloth type "E" sheet infilled with a duroplastic matrix. This is a thermoset polymer-epoxy resin with different molecular weights. The composites were fabricated by IZOERG company, which is based in Poland. The final articles were 1.5 mm thick by 60 cm long and 30 cm wide, with the glass layers arranged parallel to the thickness. Young's modulus and tensile strength were measured at room temperature. Using the thermal analysis of dynamic mechanical properties (DMTA), the values of the storage modulus and the loss modulus were determined, and the damping factor was used to determine the glass transition temperature (Tg). It was revealed that the nature of changes in the storage modulus, loss modulus, and damping factor of composite materials depends on the type of epoxy resin used. Thermal expansion is a crucial parameter when choosing a material for application in cryogenic conditions. Thanks to the TMA method, thermal expansion coefficients for composite materials were determined. The results show that the highest value of the coefficient of thermal expansion leads the laminate EP_4_2 based on brominated epoxy resin cured with novolac P. Duroplastic composites were characterized at cryogenic temperatures, and the results are interesting for developing cryogenic applications, including electric motors, generators, magnets, and other devices.
人们普遍认为,使用中的聚合物复合材料不仅经常受到复杂的机械载荷,还面临恶劣的环境条件。本文探讨了五种特定复合材料的机械和热性能。这些复合材料由填充有热固性塑料基体的“E”型玻璃布层压板组成。这是一种具有不同分子量的热固性聚合物——环氧树脂。这些复合材料由位于波兰的IZOERG公司制造。最终制品厚1.5毫米,长60厘米,宽30厘米,玻璃层平行于厚度方向排列。在室温下测量了杨氏模量和拉伸强度。通过动态机械性能热分析(DMTA)确定了储能模量和损耗模量的值,并使用阻尼因子确定玻璃化转变温度(Tg)。结果表明,复合材料的储能模量、损耗模量和阻尼因子的变化性质取决于所用环氧树脂的类型。热膨胀是选择用于低温条件的材料时的一个关键参数。借助TMA方法,确定了复合材料的热膨胀系数。结果表明,基于用酚醛清漆P固化的溴化环氧树脂的层压板EP_4_2的热膨胀系数最高。对热固性塑料复合材料在低温下进行了表征,其结果对于开发包括电动机、发电机、磁体和其他装置在内的低温应用很有意义。