Hydrogen-Bonded Metal-Organic Framework Nanosheet as a Proton Conducting Membrane for an H/O Fuel Cell.

Proton-conducting metal-organic frameworks (MOFs) have attracted attention as potential electrolytes for fuel cells. However, research progress in utilizing MOFs as electrolytes for fuel cells has been limited, mainly due to challenges associated with issues such as the fabrication of MOF membranes, and hydrogen crossover through the MOF's pores. Here, proton conductivity and fuel cell performance of a self-standing membrane prepared from of a bismuth subgallate MOF nanosheets with non-porous structure are reported. The fabricated MOF nanosheet membrane with no binding agent exhibits structural anisotropy. The proton conductivity in the membrane thickness direction (4.4 × 10 S cm) at 90 °C and RH 100% is observed to be higher than that in the in-plane direction of the membrane (3.3 × 10 S cm). The open circuit voltage (OCV) of a fuel cell with ≈120 µm proton conducting membrane is 1.0 V. The non-porous nature of the MOF nanosheets contributes to the relatively high OCV. A fuel cell using ≈40 µm membrane as proton conducting electrolyte records a maximum of 25 mW cm power density and a maximum of 109 mA cm current density with 0.91 V OCV at 80 °C in humid conditions.