Cui M S, Niu F, Ji R S, Duan L, Zhang X
Beijing Tiandi Rongchuang Technology Co. Ltd., Beijing 100011, China.
National Energy Technology & Equipment Laboratory of Coal Utilization and Emission Control, Beijing 100011, China.
ACS Omega. 2024 Mar 1;9(10):11769-11779. doi: 10.1021/acsomega.3c09231. eCollection 2024 Mar 12.
Ammonia as a fuel to partially or completely replace fossil fuels is one of the effective ways to reduce carbon dioxide, and the research on ammonia coal cocombustion is of great significance. The combustion characteristics of ammonia are very different from those of pulverized coal, resulting in the ignition and emission characteristics of ammonia and pulverized coal gas flow that is different from traditional pulverized coal flame. In this paper, the effect of pulverized coal concentration in coal and ammonia mixed combustion jet on the ignition distance and gas-phase components at different positions of the jet flame were studied experimentally on the flat flame burner, and the conditions of ignition and ignition stability of coal and ammonia gas-solid fuel were expounded. It was found that the ammonia mixed with pulverized coal changed the temperature field of the flat flame burner and therefore the ignition characteristics of the jet were changed. The ignition delay time at the same jet speed was positively correlated with the pulverized coal concentration, but when the pulverized coal concentration continued to decrease, the influence on the ignition delay time gradually became smaller. The composition of coal ammonia gas-solid fuel changed the heat transfer path and share during combustion, and finally, the flame temperature was negatively correlated with the concentration of pulverized coal. Therefore, the reduction of the pulverized coal concentration was conducive to the stable combustion of coal ammonia mixed fuel. When HAB = 100 mm, the conversion rate of fuel N to NO per unit mass of coal ammonia mixture increased with the increase of pulverized coal concentration. The NO production amount first increased and then decreased with the increase of pulverized coal concentration, and the amount of NO and NO decreased rapidly with the increase of HAB. The proportion of NO in NO exceeded 94%, which was conducive to achieving low nitrogen combustion of coal and ammonia gas-solid fuel. In general, the O concentration in the ammonia coal jet flame decreased, the flue gas temperature, and NO and CO generation increased after mixing ammonia, and the optimal pulverized coal concentration in this experiment was 0.41 kgc/kga (mass ratio of pulverized coal to the sum of N and NH).
氨作为一种部分或完全替代化石燃料的燃料,是减少二氧化碳的有效途径之一,对氨煤共燃的研究具有重要意义。氨的燃烧特性与煤粉有很大不同,导致氨与煤粉气流的着火和排放特性不同于传统煤粉火焰。本文在平面火焰燃烧器上对煤氨混合燃烧射流中煤粉浓度对射流火焰不同位置着火距离和气相组分的影响进行了实验研究,阐述了煤氨气固燃料的着火及着火稳定性条件。研究发现,氨与煤粉混合改变了平面火焰燃烧器的温度场,从而改变了射流的着火特性。在相同射流速度下,着火延迟时间与煤粉浓度呈正相关,但当煤粉浓度持续降低时,对着火延迟时间的影响逐渐变小。煤氨气固燃料的组成改变了燃烧过程中的传热路径和份额,最终火焰温度与煤粉浓度呈负相关。因此,降低煤粉浓度有利于煤氨混合燃料的稳定燃烧。当HAB = 100 mm时,单位质量煤氨混合物中燃料N向NO的转化率随煤粉浓度的增加而增加。NO生成量随煤粉浓度的增加先增加后减少,且NO和NO的量随HAB的增加而迅速降低。NO在NO中的比例超过94%,有利于实现煤氨气固燃料的低氮燃烧。总体而言,氨加入后氨煤射流火焰中的O浓度降低,烟气温度、NO和CO生成量增加,本实验中最佳煤粉浓度为0.41 kgc/kga(煤粉与N和NH总和的质量比)。