Liu Wenfeng, Zhou Ziyou, Zhou Jicheng
School of Energy Science and Engineering, Central South University, Changsha, China.
School of Materials Science and Engineering, Central South University, Changsha, China.
Front Chem. 2024 Mar 4;12:1378332. doi: 10.3389/fchem.2024.1378332. eCollection 2024.
In this study, we used the solar cell capacitance simulator (SCAPS) to analyse numerically the performance of perovskite solar cells (PSCs) containing CHNHPbI. The findings indicate that P-N homologous junction processing based on traditional P-I-N PSCs can enhance the photoelectric conversion efficiency (PCE). Furthermore, the authors analyzed the effect of uniform P-N doping of CHNHPbI, concluding that the photoelectric efficiency can be improved from 16.10% to 19.03% after doping. In addition, the optical properties of PSCs under solar irradiation are simulated using finite difference time-domain (FDTD) software under AM1.5. This method is applied to investigate the effect of the P-N uniform junction on the internal electric field generated within the cell. The generation of this electric field promotes carrier separation and transmission, ultimately increasing the open circuit voltage (V) of the solar cell from 1.03 to 1.12 V. The usage of P-N junctions enhances PSCs performance and exhibits vast potential for designing and developing PSCs.
在本研究中,我们使用太阳能电池电容模拟器(SCAPS)对含有CHNHPbI的钙钛矿太阳能电池(PSC)的性能进行了数值分析。研究结果表明,基于传统P-I-N PSC的P-N同源结处理可以提高光电转换效率(PCE)。此外,作者分析了CHNHPbI均匀P-N掺杂的影响,得出掺杂后光电效率可从16.10%提高到19.03%的结论。另外,使用有限时域差分(FDTD)软件在AM1.5条件下模拟了太阳能辐射下PSC的光学特性。该方法用于研究P-N均匀结对电池内部产生的内电场的影响。这种电场的产生促进了载流子的分离和传输,最终使太阳能电池的开路电压(V)从1.03 V提高到1.12 V。P-N结的使用提高了PSC的性能,并在PSC的设计和开发方面展现出巨大潜力。