Zhou Zhengqing, Liu Yuzhe, Jiang Huiling, Bai Zhiming, Sun Lingxia, Liu Jia, Zhao Wenwen
Research Institute of Macro-Safety Science, University of Science and Technology Beijing, Beijing 100083, China.
School of Civil and Resource Engineering, University of Science and Technology Beijing, Beijing 100083, China.
Toxics. 2024 Feb 28;12(3):184. doi: 10.3390/toxics12030184.
In order to investigate the impact of environmental temperature and atmospheric humidity on the leakage and diffusion of hydrogen fluoride (HF) gas, this study focused on the real scenario of an HF chemical industrial park. Based on the actual dispersion scenario of HF gas, a proportionally scaled-down experimental platform for HF gas leakage was established to validate the accuracy and feasibility of numerical simulations under complex conditions. Using the validated model, the study calculated the complex scenarios of HF leakage and diffusion within the temperature range of 293 K to 313 K and the humidity range of 0% to 100%. The simulation results indicated that different environmental temperatures had a relatively small impact on the hazardous areas (the lethal area, severe injury area, light injury area, and maximum allowable concentration (MAC) area) formed by HF gas leakage. At 600 s of dispersion, the fluctuation range of hazardous area sizes under different temperature conditions was between 3.11% and 13.07%. In contrast to environmental temperature, atmospheric relative humidity had a more significant impact on the dispersion trend of HF leakage. Different relative humidity levels mainly affected the areas of the lethal zone, light injury zone, and MAC zone. When HF continued to leak and disperse for 600 s, compared to 0% relative humidity, 100% relative humidity reduced the lethal area by 35.7%, while increasing the light injury area and MAC area by 27.26% and 111.6%, respectively. The impact on the severe injury area was relatively small, decreasing by 1.68%. The results of this study are crucial for understanding the dispersion patterns of HF gas under different temperature and humidity conditions.
为了研究环境温度和大气湿度对氟化氢(HF)气体泄漏与扩散的影响,本研究聚焦于某HF化工园区的实际场景。基于HF气体的实际扩散场景,搭建了按比例缩小的HF气体泄漏实验平台,以验证复杂条件下数值模拟的准确性和可行性。利用验证后的模型,本研究计算了在293 K至313 K温度范围和0%至100%湿度范围内HF泄漏与扩散的复杂场景。模拟结果表明,不同环境温度对HF气体泄漏形成的危险区域(致死区、重伤区、轻伤区和最大允许浓度(MAC)区)影响相对较小。在扩散600 s时,不同温度条件下危险区域大小的波动范围在3.11%至13.07%之间。与环境温度相比,大气相对湿度对HF泄漏的扩散趋势影响更为显著。不同相对湿度水平主要影响致死区、轻伤区和MAC区的面积。当HF持续泄漏扩散600 s时,与相对湿度0%相比,相对湿度100%时致死区面积减少35.7%,而轻伤区面积和MAC区面积分别增加27.26%和111.6%。对重伤区的影响相对较小,减少了1.68%。本研究结果对于理解不同温度和湿度条件下HF气体的扩散模式至关重要。