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改性纳米晶纤维素稳定的可逆乳液钻井液的制备与性能

Preparation and Properties of Reversible Emulsion Drilling Fluid Stabilized by Modified Nanocrystalline Cellulose.

作者信息

Liu Fei, Li Yongfei, Wang Xuewu, Xia Zhizeng

机构信息

College of Petroleum Engineering, Shandong Institute of Petroleum and Chemical Technology, Dongying 257061, China.

Chemistry and Chemical Engineering, Xi'an Shiyou University, Xi'an 710065, China.

出版信息

Molecules. 2024 Mar 13;29(6):1269. doi: 10.3390/molecules29061269.

Abstract

Reversible emulsion drilling fluids can concentrate the advantages of water-based drilling fluids and oil-based drilling fluids. Most of the existing reversible emulsion drilling fluid systems are surfactant-based emulsifier systems, which have the disadvantage of poor stability. However, the use of modified nanoparticles as emulsifiers can significantly enhance the stability of reversible emulsion drilling fluids, but ordinary nanoparticles have the disadvantages of high cost and easily causing environmental pollution. In order to solve the shortcomings of the existing reversible emulsion drilling fluid system, the modified nanocrystalline cellulose was considered to be used as an emulsifier to prepare reversible emulsion drilling fluid. After research, the modified nanocrystalline cellulose NWX-3 can be used to prepare reversible emulsions, and on this basis, reversible emulsion drilling fluids can be constructed. Compared with the reversible emulsion drilling fluid stabilized by HRW-DMOB (1.3 vol.% emulsifier), the reversible emulsion drilling fluid stabilized by the emulsifier NWX-3 maintained a good reversible phase performance, filter cake removal, and oily drill cuttings treatment performance with less reuse of emulsifier (0.8 vol.%). In terms of temperature resistance (150 °C) and stability (1000 V < W/O emulsion demulsification voltage), it is significantly better than that of the surfactant system (temperature resistance 120 °C, 600 V < W/O emulsion demulsification voltage < 650 V). The damage of reservoir permeability of different types of drilling fluids was compared by physical simulation, and the damage order of core gas permeability was clarified: water-based drilling fluid > reversible emulsion drilling fluid > oil-based drilling fluid. Furthermore, the NMR states of different types of drilling fluids were compared as working fluids, and the main cause of core permeability damage was the retention of intrusive fluids in the core.

摘要

可逆乳化钻井液可以集中水基钻井液和油基钻井液的优点。现有的大多数可逆乳化钻井液体系都是基于表面活性剂的乳化剂体系,存在稳定性差的缺点。然而,使用改性纳米颗粒作为乳化剂可以显著提高可逆乳化钻井液的稳定性,但普通纳米颗粒存在成本高和易造成环境污染的缺点。为了解决现有可逆乳化钻井液体系的不足,考虑使用改性纳米晶纤维素作为乳化剂来制备可逆乳化钻井液。经过研究,改性纳米晶纤维素NWX - 3可用于制备可逆乳液,并在此基础上构建可逆乳化钻井液。与由HRW - DMOB(1.3体积%乳化剂)稳定的可逆乳化钻井液相比,由乳化剂NWX - 3稳定的可逆乳化钻井液在乳化剂用量较少(0.8体积%)的情况下,保持了良好的可逆相性能、滤饼清除性能和含油钻屑处理性能。在耐温性(150℃)和稳定性(W/O乳液破乳电压>1000V)方面,明显优于表面活性剂体系(耐温性120℃,600V<W/O乳液破乳电压<650V)。通过物理模拟比较了不同类型钻井液对储层渗透率的损害,明确了岩心气测渗透率的损害顺序:水基钻井液>可逆乳化钻井液>油基钻井液。此外,比较了不同类型钻井液作为工作流体时的核磁共振状态,发现岩心渗透率损害的主要原因是侵入流体在岩心中的滞留。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9a03/10975334/957f32c0db58/molecules-29-01269-g001.jpg

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