Abdelaziz Omar Y, Vives Mariona Battestini, Mankar Smita V, Warlin Niklas, Nguyen Tran Tam, Zhang Baozhong, Hulteberg Christian P, Khataee Amirreza
Department of Chemical Engineering, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia.
Interdisciplinary Research Center for Refining & Advanced Chemicals, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia.
iScience. 2024 Mar 4;27(4):109418. doi: 10.1016/j.isci.2024.109418. eCollection 2024 Apr 19.
Lignin is an abundant polyaromatic polymer with a wide range of potential future uses. However, the conversion of lignin into valuable products comes at a cost, and medium- to high-value applications are thus appropriate. Two examples of these are polymers (e.g., as fibers, plasticizers, or additives) and flow batteries (e.g., as redox species). Both of these areas would benefit from lignin-derived molecules with potentially low molecular weight and high (electro)chemical functionality. A promising route to obtain these molecules is oxidative lignin depolymerization, as it enables the formation of targeted compounds with multiple functionalities. An application with high potential in the production of plastics is the synthesis of new sustainable polymers. Employing organic molecules, such as quinones and heterocycles, would constitute an important step toward the sustainability of aqueous flow batteries, and lignin and its derivatives are emerging as redox species, mainly due to their low cost and renewability.
木质素是一种丰富的多芳族聚合物,具有广泛的潜在未来用途。然而,将木质素转化为有价值的产品是有成本的,因此中高价值应用是合适的。其中两个例子是聚合物(例如,作为纤维、增塑剂或添加剂)和液流电池(例如,作为氧化还原物质)。这两个领域都将受益于具有潜在低分子量和高(电)化学功能的木质素衍生分子。获得这些分子的一条有前途的途径是氧化木质素解聚,因为它能够形成具有多种功能的目标化合物。在塑料生产中具有高潜力的一个应用是合成新的可持续聚合物。使用有机分子,如醌和杂环化合物,将是迈向水性液流电池可持续性的重要一步,并且木质素及其衍生物正作为氧化还原物质出现,主要是由于它们的低成本和可再生性。