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通过高效可见光固化实现用于可折叠显示器的紫外线阻挡光学透明粘合剂。

Ultraviolet light blocking optically clear adhesives for foldable displays via highly efficient visible-light curing.

作者信息

Kwon Yonghwan, Lee Seokju, Kim Junkyu, Jun Jinwon, Jeon Woojin, Park Youngjoo, Kim Hyun-Joong, Gierschner Johannes, Lee Jaesang, Kim Youngdo, Kwon Min Sang

机构信息

Department of Materials Science and Engineering, Seoul National University, Seoul, Republic of Korea.

Department of Electrical and Computer Engineering, Seoul National University, Seoul, Republic of Korea.

出版信息

Nat Commun. 2024 Apr 2;15(1):2829. doi: 10.1038/s41467-024-47104-y.

Abstract

In developing an organic light-emitting diode (OLED) panel for a foldable smartphone (specifically, a color filter on encapsulation) aimed at reducing power consumption, the use of a new optically clear adhesive (OCA) that blocks UV light was crucial. However, the incorporation of a UV-blocking agent within the OCA presented a challenge, as it restricted the traditional UV-curing methods commonly used in the manufacturing process. Although a visible-light curing technique for producing UV-blocking OCA was proposed, its slow curing speed posed a barrier to commercialization. Our study introduces a highly efficient photo-initiating system (PIS) for the rapid production of UV-blocking OCAs utilizing visible light. We have carefully selected the photocatalyst (PC) to minimize electron and energy transfer to UV-blocking agents and have chosen co-initiators that allow for faster electron transfer and more rapid PC regeneration compared to previously established amine-based co-initiators. This advancement enabled a tenfold increase in the production speed of UV-blocking OCAs, while maintaining their essential protective, transparent, and flexible properties. When applied to OLED devices, this OCA demonstrated UV protection, suggesting its potential for broader application in the safeguarding of various smart devices.

摘要

在开发一款旨在降低功耗的可折叠智能手机有机发光二极管(OLED)面板(具体而言,是封装上的彩色滤光片)时,使用一种能阻挡紫外线的新型光学透明粘合剂(OCA)至关重要。然而,在OCA中加入紫外线阻挡剂带来了挑战,因为这限制了制造过程中常用的传统紫外线固化方法。尽管有人提出了一种用于生产紫外线阻挡OCA的可见光固化技术,但其缓慢的固化速度成为商业化的障碍。我们的研究引入了一种高效的光引发体系(PIS),用于利用可见光快速生产紫外线阻挡OCA。我们精心挑选了光催化剂(PC),以尽量减少电子和能量向紫外线阻挡剂的转移,并选择了与先前已确立的胺基共引发剂相比能实现更快电子转移和更快速PC再生的共引发剂。这一进展使紫外线阻挡OCA的生产速度提高了十倍,同时保持了其基本的防护、透明和柔性特性。当应用于OLED器件时,这种OCA表现出紫外线防护性能,表明其在保护各种智能设备方面具有更广泛应用的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd37/10987679/515656ea0639/41467_2024_47104_Fig1_HTML.jpg

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