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在原子水平上理解PtAg(SPhCl)纳米团簇的分解过程。

Understanding the decomposition process of the PtAg(SPhCl) nanocluster at the atomic level.

作者信息

Jiang Kefan, Ma Along, Li Yuansheng, Wang Jiawei, Yin Zhengmao, Wang Shuxin

机构信息

College of Materials Science and Engineering, Qingdao University of Science and Technology Qingdao 266042 P. R. China

Key Laboratory of Optic-Electric Sensing and Analytical Chemistry for Life Science, MOE, Shandong Key Laboratory of Biochemical Analysis, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology Qingdao 266042 China.

出版信息

RSC Adv. 2024 Apr 2;14(15):10574-10579. doi: 10.1039/d4ra01274g. eCollection 2024 Mar 26.

DOI:10.1039/d4ra01274g
PMID:38567326
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10985538/
Abstract

We report the decomposition of the PtAg(SPhCl) nanocluster into a crown-like PtAg(SR) (SR = 2,4-SPhCl and 4-SPhBr) complex. UV-vis spectra and single crystal X-ray diffraction were used to track the structure-conversion process. Based on the total structure, the differences in ligand exchange rates at different sites and the effects on the stability were mapped out. This work can not only help us understand the ligand exchange behavior of the clusters, but also provide experimental support for the design of stable metal clusters.

摘要

我们报道了PtAg(SPhCl)纳米团簇分解为冠状PtAg(SR)（SR = 2,4 - SPhCl和4 - SPhBr）配合物的过程。利用紫外可见光谱和单晶X射线衍射来追踪结构转变过程。基于整体结构，绘制出不同位点配体交换速率的差异及其对稳定性的影响。这项工作不仅有助于我们理解团簇的配体交换行为，还为稳定金属团簇的设计提供了实验支持。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f01/10985538/78ae88d138e3/d4ra01274g-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f01/10985538/e4b3df5cdabf/d4ra01274g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f01/10985538/e866a5147ad7/d4ra01274g-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f01/10985538/b65b4e38fad8/d4ra01274g-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f01/10985538/ff33e8e727c0/d4ra01274g-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f01/10985538/78ae88d138e3/d4ra01274g-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f01/10985538/e4b3df5cdabf/d4ra01274g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f01/10985538/e866a5147ad7/d4ra01274g-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f01/10985538/b65b4e38fad8/d4ra01274g-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f01/10985538/ff33e8e727c0/d4ra01274g-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4f01/10985538/78ae88d138e3/d4ra01274g-f5.jpg

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Substituent Effect to Fine-Tune Energy Levels of Atom-Precise [MoOS ] Modified Copper(I) Thiolate Clusters Boosting Recyclable Photocatalysis.
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Monoarsine-protected icosahedral cluster [Au(AsPh)Cl]: comparative studies on ligand effect and surface reactivity with its stibine analogue.单砷保护的二十面体簇合物[Au(AsPh)Cl]：与锑类似物的配体效应和表面反应性的比较研究。
Chem Sci. 2023 May 29;14(24):6564-6571. doi: 10.1039/d3sc01311a. eCollection 2023 Jun 21.
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