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4-甲基丙烯酸甲酯(4-META)在粘着性不透明树脂中的应用。(第1部分:粘着强度与稳定性(作者译))

[Application of 4-META on adhesive opaque resin. (Part 1) Adhesive strength and the stability (author's transl)].

作者信息

Tanaka T, Nagata K, Nakabayashi N, Masuhara E

出版信息

Shika Rikogaku Zasshi. 1979 Apr;20(50):79-84.

PMID:385794
Abstract

Mechanical devices, which has been conventionally used for retaining thermo-setting acrylic resin veneers possesses disadvantage of poor marginal sealing and requires rather complicated procedure applying on the metal casting. An application of adhesive resins to overcome these disadvantages was studied. Adhesive opaque resin consisted of MMA, epoxy acrylate, TiO2 and adhesive monomer 4-META was prepared and the adhesive bonding strength between the opaque resin and Ni-Cr alloy which is for crown and bridge works, was measured. As the results, the opaque resin applied on the metal casting with proper surface treatment showed an excellent adhesive bonding strength of 260 kg/cm2. This value did not decreased even after subjected to 300 time thermal cyclings (4 degrees C and 60 degrees C). After a three months immersion in water at 37 degrees C, adhesive bonding strength decreased slightly to 190 kg/cm2.

摘要

传统上用于固定热固性丙烯酸树脂贴面的机械装置存在边缘密封性差的缺点,并且在金属铸件上应用需要相当复杂的程序。研究了使用粘结树脂来克服这些缺点。制备了由甲基丙烯酸甲酯(MMA)、环氧丙烯酸酯、二氧化钛(TiO₂)和粘结单体4-甲基丙烯酰氧基乙基偏苯三酸酐(4-META)组成的粘结性遮色树脂,并测量了该遮色树脂与用于冠桥修复的镍铬合金之间的粘结强度。结果表明,经过适当表面处理后应用于金属铸件的遮色树脂显示出260 kg/cm²的优异粘结强度。即使经过300次热循环(4℃和60℃),该值也没有降低。在37℃水中浸泡三个月后,粘结强度略有下降至190 kg/cm²。

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