Clarke Brandon R, Witt Connor L, Ilton Mark, Crosby Alfred J, Watkins James J, Tew Gregory N
University of Massachusetts Amherst, Amherst, Massachusetts, 01003, United States.
Department of Physics, Harvey Mudd College, Claremont, CA 91711, United States.
Angew Chem Int Ed Engl. 2024 May 27;63(22):e202318220. doi: 10.1002/anie.202318220. Epub 2024 May 6.
Bottlebrush networks (BBNs) are an exciting new class of materials with interesting physical properties derived from their unique architecture. While great strides have been made in our fundamental understanding of bottlebrush polymers and networks, an interdisciplinary approach is necessary for the field to accelerate advancements. This review aims to act as a primer to BBN chemistry and physics for both new and current members of the community. In addition to providing an overview of contemporary BBN synthetic methods, we developed a workflow and desktop application (LengthScale), enabling bottlebrush physics to be more approachable. We conclude by addressing several topical issues and asking a series of pointed questions to stimulate conversation within the community.
刷状网络(BBNs)是一类令人兴奋的新型材料,因其独特的结构而具有有趣的物理性质。虽然我们对刷状聚合物和网络的基本理解已经取得了很大进展,但该领域要加速进步,跨学科方法是必要的。这篇综述旨在为该领域的新成员和现有成员提供BBN化学和物理的入门介绍。除了概述当代BBN的合成方法外,我们还开发了一个工作流程和桌面应用程序(LengthScale),使刷状物理更容易理解。我们通过讨论几个热门问题并提出一系列尖锐问题来结束本文,以激发该领域的讨论。