铑/亚磺酰基双膦配体与ZSM-5催化烯烃的高活性和区域选择性氢氨甲基化反应
Highly active and regioselective hydroaminomethylation of olefins catalyzed by Rh/sulfoxantphos with ZSM-5.
作者信息
Yuan Xiaoshuang, Zhang Xueqing, Zheng Zhaohui, Sun Shuhui, Jia Xiaofei, Dong Shuxiang
机构信息
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China.
Liaoning Sino More New Material Co., Ltd, Panjin, 124000, P. R. China.
出版信息
Chem Commun (Camb). 2024 Apr 25;60(35):4667-4670. doi: 10.1039/d4cc00663a.
Rh-catalyzed hydroaminomethylation has been developed with acid sulfoxantphos and ZSM-5. Linear amines were obtained in good yields (71-95%) with high l/ ratios (up to 132.4) and excellent TON values (up to 23 760). The ZSM-5 and SOH group of ligands improved the performances of hydroformylation and reductive amination.
铑催化的氢氨甲基化反应已通过酸性亚砜膦和ZSM-5得以实现。以高l/比值（高达132.4）和优异的TON值（高达23760）获得了高产率（71 - 95%）的直链胺。ZSM-5和配体的SOH基团提高了氢甲酰化和还原胺化反应的性能。
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