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板式轨道用磷酸镁水泥修补材料的早期性能

Early properties of magnesium phosphate cement repairing material used in slab track.

作者信息

Wang Ji, Gao Liang, Zhang Yanrong, Wang Ludong, Xu Chenyu

机构信息

School of Civil Engineering, Beijing Jiaotong University, Beijing, 100044, China.

Frontiers Science Center for Smart High-speed Railway System, Beijing, 100044, China.

出版信息

Heliyon. 2024 Mar 28;10(7):e28913. doi: 10.1016/j.heliyon.2024.e28913. eCollection 2024 Apr 15.

DOI:10.1016/j.heliyon.2024.e28913
PMID:38596064
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11002680/
Abstract

Magnesium phosphate cement (MPC) is a high-performance repairing material suitable for the interfacial disease of slab track. In this study, the early properties of MPC were optimized using central composite design (CCD) approach based on response surface methodology (RSM). Three factors with five levels and three responses were considered. The significance of the factors and their interactions were verified by using analysis of variance (ANOVA). The result show that the mass ratio of water-to-binder (W/b) affects fluidity, while the mass ratio of magnesia-to-phosphate (M/P) and borax-to-magnesia (B/M) impact the setting time of MPC. Higher W/b results in higher fluidity, while an increase in M/P reduces the setting time by increasing the neutralization reaction. Borax addition retards the reaction, prolonging the setting time. The three factors significantly affect the early compressive strength of MPC. At M/P = 3.5, the interweaving of MgO and K-struvite (MKP) forms a dense network structure, enhancing the strength. Borax and W/b interact to affect compressive strength, with borax retarding MKP crystal growth and higher W/b reducing compactness. Combined with microscopic property test, the strength generation mechanism of MPC with optimized mixing ratio was revealed, And the feasibility of field application of MPC was verified by strength test.

摘要

磷酸镁水泥(MPC)是一种适用于板式轨道界面病害的高性能修复材料。在本研究中,基于响应面法(RSM),采用中心复合设计(CCD)方法对MPC的早期性能进行了优化。考虑了三个因素、五个水平和三个响应。通过方差分析(ANOVA)验证了各因素及其相互作用的显著性。结果表明,水胶比(W/b)影响流动性,而氧化镁与磷酸盐的质量比(M/P)和硼砂与氧化镁的质量比(B/M)影响MPC的凝结时间。较高的W/b导致较高的流动性,而M/P的增加通过增加中和反应来缩短凝结时间。添加硼砂会延缓反应,延长凝结时间。这三个因素对MPC的早期抗压强度有显著影响。当M/P = 3.5时,氧化镁与磷酸钾镁(MKP)的交织形成致密的网络结构,提高了强度。硼砂和W/b相互作用影响抗压强度,硼砂会延缓MKP晶体生长,而较高的W/b会降低密实度。结合微观性能测试,揭示了优化配合比的MPC的强度生成机制,并通过强度测试验证了MPC现场应用的可行性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/010b/11002680/0ecea55c1c7c/gr7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/010b/11002680/68cdd65c569b/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/010b/11002680/ad546970896c/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/010b/11002680/4f2745eb609c/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/010b/11002680/18daee21d517/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/010b/11002680/2bce01073819/gr5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/010b/11002680/13aff0037f19/gr6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/010b/11002680/0ecea55c1c7c/gr7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/010b/11002680/68cdd65c569b/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/010b/11002680/ad546970896c/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/010b/11002680/4f2745eb609c/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/010b/11002680/18daee21d517/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/010b/11002680/2bce01073819/gr5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/010b/11002680/13aff0037f19/gr6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/010b/11002680/0ecea55c1c7c/gr7.jpg

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本文引用的文献

1
Investigation and Optimisation of the Rheological Properties of Magnesium Potassium Phosphate Cement with Response Surface Methodology.基于响应面法的磷酸镁钾水泥流变性能研究与优化
Materials (Basel). 2022 Sep 30;15(19):6815. doi: 10.3390/ma15196815.
2
Effect of liquid-to-solid ratios on the properties of magnesium phosphate chemically bonded ceramics.液固比对磷酸镁化学结合陶瓷性能的影响。
Mater Sci Eng C Mater Biol Appl. 2013 Jul 1;33(5):2508-12. doi: 10.1016/j.msec.2013.02.014. Epub 2013 Feb 15.