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通过电喷雾法制备RDX/F2311/FeO/Al复合空心微球及其组分间燃烧过程中的协同能量释放

Preparation of RDX/F2311/FeO/Al Composite Hollow Microspheres by Electrospray and Synergistic Energy Release during Combustion between Components.

作者信息

Zhang Zhenwei, Jiang Dong, Yang Lanting, Song Wenkui, Wang Ruihao, Huang Qiuan

机构信息

Co-Innovation Center for New Energetic Materials, Southwest University of Science and Technology, Mianyang 621010, China.

Automation Research Institute Co., Ltd. of China South Industries Group Corporation, Mianyang 621000, China.

出版信息

Materials (Basel). 2024 Apr 2;17(7):1623. doi: 10.3390/ma17071623.

Abstract

Nanothermites and high-energy explosives have significantly improved the performance of high-energy composites and have broad application prospects. Therefore, in this study, RDX/F2311/FeO/Al composite hollow microspheres were successfully prepared utilizing the electrospray method using F2311 as a binder between components. The results show that the combustion time of the composite hollow microspheres is shortened from 2400 ms to 950 ms, the combustion process is more stable, and the energy release is more concentrated. The H50 of the composite hollow microspheres increased from 14.49 cm to 24.57 cm, the explosion percentage decreased from 84% to 72%, and the sensitivity of the composite samples decreased significantly. This is mainly the result of the combination of homogeneous composition and synergistic reactions. The combustion results show that F2311 as a binder affects the tightness of the contact between the components. By adjusting its content, the combustion time and the intensity of the combustion of the composite microspheres can be adjusted, which provides a feasible direction for its practical application.

摘要

纳米铝热剂和高能炸药显著提高了高能复合材料的性能,具有广阔的应用前景。因此,在本研究中,以F2311作为组分间的粘结剂,采用电喷雾法成功制备了RDX/F2311/FeO/Al复合空心微球。结果表明,复合空心微球的燃烧时间从2400 ms缩短至950 ms,燃烧过程更稳定,能量释放更集中。复合空心微球的H50从14.49 cm增加到24.57 cm,爆炸率从84%降至72%,复合样品的敏感度显著降低。这主要是均匀组成和协同反应相结合的结果。燃烧结果表明,F2311作为粘结剂影响组分间接触的紧密程度。通过调整其含量,可以调节复合微球的燃烧时间和燃烧强度,为其实际应用提供了可行的方向。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7074/11012291/83736088adfe/materials-17-01623-g001.jpg

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