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用于光催化降解有机染料的钼酸锶抑制磁性壳聚糖多糖复合材料的制备

Fabrication of MoS restrained magnetic chitosan polysaccharide composite for the photocatalytic degradation of organic dyes.

作者信息

Sirajudheen Palliyalil, Vigneshwaran Sivakumar, Thomas Nygil, Selvaraj Manickam, Venkatesan Kumar, Park Chang Min

机构信息

Department of Chemistry, Pocker Sahib Memorial Orphanage College, Tirurangadi, Malappuram, Kerala 676306, India.

Environmental System Laboratory, Department of Civil Engineering, Kyung Hee University-Global Campus, 1732 Deogyong-daero, Giheung-Gu, Yongin-Si, Gyeonggi-Do 16705, Republic of Korea.

出版信息

Carbohydr Polym. 2024 Jul 1;335:122071. doi: 10.1016/j.carbpol.2024.122071. Epub 2024 Mar 18.

DOI:10.1016/j.carbpol.2024.122071
PMID:38616093
Abstract

Chitosan (CS) polysaccharide is expected to exhibit greater ionic conductivity, which can be attributed to its increased amino group content when it is blended with different semiconducting materials. Herein, the work used this conducting ability of chitosan and prepared a heterogeneous MoS-induced magnetic chitosan (MF@CS) composite via the co-precipitation method, which was used to scrutinize the catalytic performance with Methylene Blue (MB) and Malachite Green (MG) dyes by visible light irradiation. The saturation magnetization value of the MF@CS composite is found to be 7.8 emu/g, which is less when compared to that of pristine FeO (55.7 emu/g) particles. The bandgap of the MF@CS composite is ∼ 2.17eV, which exceeds the bandgap (E) of bare MoS of 1.80 eV. The maximum color removal of 96.3 % and 93.4 % for MB and MG dyestuffs is recognized in the exposure of the visible spectrum, respectively. At a starting dye dosage of 30 mg/L, 0.1 g/L of MF@CS, a pH level of 8-11, and 70 min of contact with direct light. The photocatalyst provides extremely good durability for a maximum of five phases. Hence, the MF@CS matrix is a viable and appropriate substance for the efficient treatment of effluents containing dye molecules.

摘要

壳聚糖(CS)多糖有望表现出更高的离子导电性,这可归因于其与不同半导体材料混合时氨基含量的增加。在此,这项工作利用了壳聚糖的这种导电能力,通过共沉淀法制备了一种非均相的钼硫化物诱导磁性壳聚糖(MF@CS)复合材料,该复合材料用于通过可见光照射来研究对亚甲基蓝(MB)和孔雀石绿(MG)染料的催化性能。发现MF@CS复合材料的饱和磁化强度值为7.8 emu/g,与原始FeO(55.7 emu/g)颗粒相比更低。MF@CS复合材料的带隙约为2.17eV,超过了裸钼硫化物的带隙(E)1.80 eV。在可见光谱照射下,MB和MG染料的最大脱色率分别为96.3%和93.4%。在初始染料剂量为30 mg/L、MF@CS为0.1 g/L、pH值为8 - 11且直接光照接触70分钟的条件下。该光催化剂在最多五个阶段内具有极佳的耐久性。因此,MF@CS基质是一种可行且合适的物质,可用于高效处理含有染料分子的废水。

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