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通过无铂族金属(氧)氢氧化物阳极实现太阳能驱动的碱性阴离子交换膜电解槽,太阳能到氢能的转换效率为12.44% 。

Solar-Powered AEM Electrolyzer via PGM-Free (Oxy)hydroxide Anode with Solar to Hydrogen Conversion Efficiency of 12.44.

作者信息

Ha Jun Seok, Park Youngtae, Jeong Jae-Yeop, Lee Seung Hun, Lee Sung Jun, Kim In Tae, Park Seo Hyun, Jin Hyunsoo, Kim Soo Min, Choi Suwon, Kim Chiho, Choi Sung Mook, Kang Bong Kyun, Lee Hyuck Mo, Park Yoo Sei

机构信息

Department of Advanced Material Engineering, Chungbuk National University, Chungdae-ro 1, Seowon-Gu, Cheongju, Chungbuk, 28644, Republic of Korea.

Department of Materials Science and Engineering, Korea Advanced Institute of Science and Engineering (KAIST), Daejeon, 34141, Republic of Korea.

出版信息

Adv Sci (Weinh). 2024 Jul;11(25):e2401782. doi: 10.1002/advs.202401782. Epub 2024 Apr 24.

DOI:10.1002/advs.202401782
PMID:38654698
原文链接:
https://pmc.ncbi.nlm.nih.gov/articles/PMC11220676/
Abstract

Water electrolyzers powered by renewable energy are emerging as clean and sustainable technology for producing hydrogen without carbon emissions. Specifically, anion exchange membrane (AEM) electrolyzers utilizing non-platinum group metal (non-PGM) catalysts have garnered attention as a cost-effective method for hydrogen production, especially when integrated with solar cells. Nonetheless, the progress of such integrated systems is hindered by inadequate water electrolysis efficiency, primarily caused by poor oxygen evolution reaction (OER) electrodes. To address this issue, a NiFeCo─OOH has developed as an OER electrocatalyst and successfully demonstrated its efficacy in an AEM electrolyzer, which is powered by renewable electricity and integrated with a silicon solar cell.

摘要

由可再生能源驱动的水电解槽正在成为一种清洁且可持续的技术,用于生产无碳排放的氢气。具体而言,利用非铂族金属(non-PGM)催化剂的阴离子交换膜(AEM)电解槽作为一种具有成本效益的制氢方法受到了关注,尤其是与太阳能电池集成时。尽管如此,这种集成系统的进展受到水电解效率不足的阻碍,这主要是由析氧反应(OER)电极性能不佳导致的。为了解决这个问题,一种NiFeCo─OOH已被开发作为OER电催化剂,并成功在由可再生电力驱动并与硅太阳能电池集成的AEM电解槽中证明了其有效性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0a77/11220676/60e9059d22b4/ADVS-11-2401782-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0a77/11220676/9598023c79ef/ADVS-11-2401782-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0a77/11220676/64d70ce7a8b0/ADVS-11-2401782-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0a77/11220676/dc4263849ae6/ADVS-11-2401782-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0a77/11220676/70dde632e17f/ADVS-11-2401782-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0a77/11220676/60e9059d22b4/ADVS-11-2401782-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0a77/11220676/9598023c79ef/ADVS-11-2401782-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0a77/11220676/64d70ce7a8b0/ADVS-11-2401782-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0a77/11220676/dc4263849ae6/ADVS-11-2401782-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0a77/11220676/70dde632e17f/ADVS-11-2401782-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0a77/11220676/60e9059d22b4/ADVS-11-2401782-g004.jpg

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本文引用的文献

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Promoting the electrocatalytic oxygen evolution reaction on NiCoO with infrared-thermal effect: A strategy to utilize the infrared solar energy to reduce activation energy during water splitting.利用红外热效应促进 NiCoO 的析氧电催化反应:一种利用红外太阳能降低水分解过程中活化能的策略。
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Ni, Co, and Yb Cation Co-doping and Defect Engineering of FeOOH Nanorods as an Electrocatalyst for the Oxygen Evolution Reaction.镍、钴和镱阳离子共掺杂及缺陷工程对FeOOH纳米棒作为析氧反应电催化剂的影响
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零间隙碱性水电解中停机后防止反向电流的阴极保护系统。
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Promoting electrocatalytic overall water splitting by sulfur incorporation into CoFe-(oxy)hydroxide.通过将硫掺入氢氧化钴铁中促进电催化全水解
Nanoscale Adv. 2021 Sep 9;3(22):6386-6394. doi: 10.1039/d1na00486g. eCollection 2021 Nov 9.
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Constructing nickel-iron oxyhydroxides integrated with iron oxides by microorganism corrosion for oxygen evolution.通过微生物腐蚀构建镍铁氧氢氧化物与氧化铁的整合体用于氧气析出。
Proc Natl Acad Sci U S A. 2022 May 17;119(20):e2202812119. doi: 10.1073/pnas.2202812119. Epub 2022 May 9.
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Activating lattice oxygen in NiFe-based (oxy)hydroxide for water electrolysis.激活镍铁基(羟基)氧化物中的晶格氧用于水电解。
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7
3D-printed NiFe-layered double hydroxide pyramid electrodes for enhanced electrocatalytic oxygen evolution reaction.用于增强电催化析氧反应的3D打印镍铁层状双氢氧化物金字塔电极
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Cost-effective and efficient water and urea oxidation catalysis using nickel-iron oxyhydroxide nanosheets synthesized by an ultrafast method.使用超快方法合成的氢氧化镍铁纳米片进行具有成本效益和高效的水和尿素氧化催化。
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