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纳米向日葵灰和纳米核桃壳灰对可持续轻质自密实混凝土性能的影响。

The influence of nanosunflower ash and nanowalnut shell ash on sustainable lightweight self-compacting concrete characteristics.

作者信息

Hilal Nahla, Hamah Sor Nadhim, Hadzima-Nyarko Marijana, Radu Dorin, Tawfik Taher A

机构信息

Scientific Affairs Department, University of Fallujah, Fallujah, Iraq.

Civil Engineering Department, University of Garmian, Kalar, Kurdistan Region, Iraq.

出版信息

Sci Rep. 2024 Apr 24;14(1):9450. doi: 10.1038/s41598-024-60096-5.

Abstract

The absence of biodegradability exhibited by plastics is a matter of significant concern among environmentalists and scientists on a global scale. Therefore, it is essential to figure out potential pathways for the use of recycled plastics. The prospective applications of its utilisation in concrete are noteworthy. The use of recycled plastic into concrete, either as a partial or complete substitution for natural aggregates, addresses the issue of its proper disposal besides contributing to the preservation of natural aggregate resources. Furthermore, the use of agricultural wastes has been regarded as a very promising waste-based substance in the industry of concrete manufacturing, with the aim of fostering the creation of an environmentally sustainable construction material. This paper illustrates the impact of nano sunflower ash (NSFA) and nano walnut shells ash (NWSA) on durability (compressive strength and density after exposure to 800 °C and sulphate attack), mechanical properties (flexural, splitting tensile and compressive strength) and fresh characteristics (slump flow diameter, T50, V-funnel flow time, L-box height ratio, segregation resistance and density) of lightweight self-compacting concrete (LWSCC). The waste walnut shells and local Iraqi sunflower were calcinated at 700 ± 50 °C for 2 h and milled for 3 h using ball milling for producing NSFA and NWSA. The ball milling succeeded in reducing the particle size lower than 75 nm for NSFA and NWSA. The preparation of seven LWSCC concrete mixes was carried out to obtain a control mix, three mixtures were created using 10%, 20% and 30% NWSA, and the other three mixtures included 10%, 20% and 30% NSFA. The normal weight coarse aggregates were substituted by the plastic waste lightweight coarse aggregate with a ratio of 75%. The fresh LWSCC passing capacity, segregation resistance, and filling capability were evaluated. The hardened characteristics of LWSCC were evaluated by determining the flexural and splitting tensile strength at 7, 14 and 28 days and the compressive strength was measured at 7, 14, 28 and 60 days. Dry density and compressive strength were measured after exposing mixes to a temperature of 800 °C for 3 h and immersed in 10% magnesium sulphate attack. The results demonstrated that the LWSCC mechanical characteristics were reduced when the percentages of NWSA and NSFA increased, except for 10% NWSA substitution ratio which had an increase in splitting tensile strength test and similar flexural strength test to the control mixture. A minor change in mechanical characteristics was observed within the results of LWSCC dry density and compressive strength incorporating various NSFA and NWSA` contents after exposing to temperature 800 °C and immersed in 10% magnesium sulphate attack. Furthermore, according to the findings, it is possible to use a combination of materials consisting of 10-20% NSFA and 10-20% NWSA to produce LWSCC.

摘要

塑料缺乏生物降解性这一问题在全球范围内受到环保主义者和科学家的高度关注。因此,找出回收塑料的潜在用途至关重要。其在混凝土中的潜在应用值得关注。将回收塑料用于混凝土,无论是部分还是完全替代天然骨料,除了解决其妥善处置问题外,还有助于保护天然骨料资源。此外,农业废弃物的使用在混凝土制造行业中被视为一种非常有前景的废弃基材料,旨在促进环保型建筑材料的生产。本文阐述了纳米向日葵灰(NSFA)和纳米核桃壳灰(NWSA)对轻质自密实混凝土(LWSCC)耐久性(800℃高温和硫酸盐侵蚀后的抗压强度和密度)、力学性能(抗折、劈裂抗拉和抗压强度)以及新拌性能(坍落度扩展直径、T50、V型漏斗流动时间、L型箱高度比、抗离析性和密度)的影响。将废弃核桃壳和伊拉克当地向日葵在700±50℃下煅烧2小时,然后使用球磨机研磨3小时以生产NSFA和NWSA。球磨成功地将NSFA和NWSA的粒径降低到75纳米以下。制备了七种LWSCC混凝土混合料,以获得一个对照混合料,三种混合料使用10%、20%和30%的NWSA配制,另外三种混合料包含10%、20%和30%的NSFA。普通重量的粗骨料被塑料废弃物轻质粗骨料以75% 的比例替代。对新拌LWSCC的通过能力、抗离析性和填充能力进行了评估。通过测定7天、14天和28天的抗折和劈裂抗拉强度以及7天、14天、28天和60天的抗压强度来评估LWSCC的硬化特性。在将混合料在800℃温度下暴露3小时并浸泡在10%硫酸镁侵蚀后,测量干密度和抗压强度。结果表明,当NWSA和NSFA的百分比增加时,LWSCC的力学性能降低,但10% NWSA替代率的混合料在劈裂抗拉强度试验中有提高,且抗折强度试验与对照混合料相似。在暴露于800℃温度并浸泡在10%硫酸镁侵蚀后,包含不同NSFA和NWSA含量的LWSCC干密度和抗压强度结果中观察到力学性能有微小变化。此外,根据研究结果,可以使用由10 - 20% NSFA和10 - 20% NWSA组成的材料组合来生产LWSCC。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/abff/11043436/31006ed4f1ea/41598_2024_60096_Fig1_HTML.jpg

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