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离子交换树脂去除葡萄酒蒸馏残液中的铜(II)及其残余溶液的再利用

Removal of Cu (II) by ion exchange resin and its re-utilization of the residual solution from the distilled wine.

作者信息

Dang Yan, Zhang Qing-An, Zhao Zhi-Hui

机构信息

Institute of Food & Physical Field Processing, School of Food Engineering and Nutrition Sciences, Shaanxi Normal University, Xi'an 710062, Shaanxi Province, PR China.

Ningxiahong Medlar Industry Group Company Limited, Zhongwei 755100, Ningxia Province, PR China.

出版信息

Food Chem X. 2024 Apr 12;22:101380. doi: 10.1016/j.fochx.2024.101380. eCollection 2024 Jun 30.

Abstract

In order to re-utilize the residual from the distillation of the Chinese wolfberry wine and reduce the environmental pollution, the residual is firstly filtered by the ceramic membrane of 50 nm, then the Cu (II) has transferred from the distillation is removed using the ion exchange resin, and the treated solution is recombined with the distilled liquor to make the Chinese wolfberry brandy and the comparison has conducted on the physicochemical properties, antioxidant activity and flavor compounds between the recombined brandy and the finished brandy. The results indicate that the Cu (II) was effectively removed by ceramic membrane combined with the D401 resin. Compared with finished brandy, the recombined brandy contains high contents of polysaccharides, phenols and flavonoids, thus contributing to the improvement of antioxidant capacity. The gas chromatography-ion mobility spectrometry (GC-IMS) reveals that 25 volatile compounds like esters and alcohols have identified in the brandy samples, and the differences are significant between the recombined and the finished brandy. In summary, the distilled residual from the Chinese wolfberry wine might be re-used after the appropriate treatment so as to reduce the discharge and environmental pollution.

摘要

为了重新利用枸杞酒蒸馏残渣,减少环境污染,首先用50纳米的陶瓷膜对残渣进行过滤,然后用离子交换树脂去除蒸馏液中转移的铜(II),将处理后的溶液与蒸馏酒重新混合制成枸杞白兰地,并对重新组合的白兰地和成品白兰地的理化性质、抗氧化活性和风味化合物进行了比较。结果表明,陶瓷膜结合D401树脂能有效去除铜(II)。与成品白兰地相比,重新组合的白兰地含有较高含量的多糖、酚类和黄酮类化合物,从而有助于提高抗氧化能力。气相色谱-离子迁移谱(GC-IMS)显示,白兰地样品中鉴定出25种挥发性化合物,如酯类和醇类,重新组合的白兰地和成品白兰地之间的差异显著。综上所述,枸杞酒蒸馏残渣经过适当处理后可以重新利用,以减少排放和环境污染。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8748/11043811/b995e2a7ee57/gr1.jpg

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