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韩国使用气相色谱-串联质谱法对水产品中农药残留进行监测和风险评估

Monitoring and Risk Assessment of Pesticide Residues in Fishery Products Using GC-MS/MS in South Korea.

作者信息

Kim Myungheon, Cho Mihyun, Kim Seo-Hong, Lee Yoonmi, Jo Mi-Ra, Moon Yong-Sun, Im Moo-Hyeog

机构信息

Department of Food Engineering, Daegu University, Gyeongsan 38453, Republic of Korea.

Department of Environmental and Biological Chemistry, Chungbuk National University, Gyeong 28644, Republic of Korea.

出版信息

Toxics. 2024 Apr 18;12(4):299. doi: 10.3390/toxics12040299.

Abstract

The aim of this study was to assess the risk of pesticide contamination in aquaculture and its impact on fishery products. We conducted an assessment of 300 samples collected from nine regions in South Korea, including various types of seafood, such as freshwater fish, marine fish, crustaceans, and shellfish. Pesticide residues in seafood were analyzed using GC-MS/MS after sample preparation using a modified QuEChERS method, revealing the presence of eight pesticides (4,4'-DDE, 4,4'-DDT, boscalid, isoprothiolane, oxadiazon, pendimethalin, thifluzamide, and trifluralin) across seven fish species (carp, far eastern catfish, crucian carp, eel, Chinese muddy loach, mirror carp, and sea bass). Following the grouping of DDE with DDT, a risk assessment of fishery products was conducted. After the estimated daily intake (EDI) of fish was calculated and compared with the acceptable daily intake (ADI), the health risk index (HI, %ADI) of the detected pesticides was evaluated and found to be 1.07% or lower. The results suggest that the consumption of domestically farmed fish products in South Korea poses minimal health risks associated with pesticide residues.

摘要

本研究的目的是评估水产养殖中农药污染的风险及其对渔业产品的影响。我们对从韩国九个地区采集的300个样本进行了评估,这些样本包括各种类型的海鲜,如淡水鱼、海鱼、甲壳类动物和贝类。使用改良的QuEChERS方法进行样品制备后,采用GC-MS/MS分析海鲜中的农药残留,结果显示在七种鱼类(鲤鱼、远东鲶鱼、鲫鱼、鳗鱼、中华泥鳅、镜鲤和鲈鱼)中检测到八种农药(4,4'-滴滴伊、4,4'-滴滴涕、啶酰菌胺、异稻瘟净、恶草酮、二甲戊灵、噻氟酰胺和氟乐灵)。将滴滴伊与滴滴涕归为一组后,对渔业产品进行了风险评估。在计算鱼类的估计每日摄入量(EDI)并与可接受的每日摄入量(ADI)进行比较后,对检测到的农药的健康风险指数(HI,%ADI)进行了评估,结果发现其为1.07%或更低。结果表明,韩国国内养殖的鱼类产品消费所带来的与农药残留相关的健康风险极小。

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