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双马来酰亚胺树脂基复合材料的制备与表征

Preparation and Characterization of Bismaleimide-Resin-Based Composite Materials.

作者信息

Liang Lingrui, Wang Pei, Li Zhihong, Zhu Yumei

机构信息

Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China.

出版信息

Materials (Basel). 2024 Apr 10;17(8):1727. doi: 10.3390/ma17081727.

Abstract

This study utilized bismaleimide (BMI) resin, reinforced with introduced ether bonds, as a binding matrix, in combination with silicon carbide (SiC), for the fabrication of composite materials. A thorough investigation was conducted to assess the influence of diverse processing parameters on the mechanical properties and high-temperature thermo-oxidative stability of these composites. Experimental results indicate a notable improvement in the mechanical properties of the composites upon the incorporation of ether bonds, in contrast to their unmodified counterparts. The variation in performance among composites with different ratios and molding densities is apparent. Within a certain range, an increase in resin content and molding density is correlated with improved bending strength in the composites. With a resin content of 27.5 vol% and a molding density of 2.31 g/cm, the composite achieved a maximum flexural strength of 109.52 MPa, representing a 24% increase compared to its pre-modification state. Even after exposure to high-temperature heat treatment, the composites displayed commendable mechanical properties compared to their pre-ether bond modification counterparts, maintaining 74.5% of the strength of the untreated composites at 300 °C. The scanning electron microscopy (SEM) microstructures of composite materials correlate remarkably well with their mechanical properties.

摘要

本研究采用引入醚键增强的双马来酰亚胺(BMI)树脂作为粘结基体,并与碳化硅(SiC)结合,用于制造复合材料。进行了全面研究,以评估各种加工参数对这些复合材料的力学性能和高温热氧化稳定性的影响。实验结果表明,与未改性的复合材料相比,引入醚键后复合材料的力学性能有显著改善。不同比例和成型密度的复合材料之间性能差异明显。在一定范围内,树脂含量和成型密度的增加与复合材料弯曲强度的提高相关。当树脂含量为27.5体积%且成型密度为2.31 g/cm时,该复合材料的最大弯曲强度达到109.52 MPa,比其改性前状态提高了24%。即使经过高温热处理,与醚键改性前的复合材料相比,这些复合材料仍表现出良好的力学性能,在300°C时保持未处理复合材料强度的74.5%。复合材料的扫描电子显微镜(SEM)微观结构与其力学性能显著相关。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3872/11051448/bad92589770e/materials-17-01727-g001.jpg

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