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低温NaO-BO-SiO玻璃化粘结剂的溶胶-凝胶合成及采用模压和破碎法制备高强度叠层磨具的研究

Research on Sol-Gel Synthesis of Low-Temperature NaO-BO-SiO Vitrified Bonds and Preparation of High-Strength Stacked Abrasives Using the Molding and Crushing Method.

作者信息

Wang Pei, Liang Lingrui, Li Zhihong, Zhu Yumei

机构信息

Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China.

出版信息

Materials (Basel). 2024 Apr 14;17(8):1799. doi: 10.3390/ma17081799.

Abstract

Currently, the sol-gel technique is employed in the synthesis of high-performance vitrified bonds; however, its application in the fabrication of stacked abrasives has been minimally explored. Furthermore, the methods utilized in the production of abrasive particles for stacked abrasives are technically challenging and incur high costs, which hinders their actual industrial application. Consequently, this study utilizes the sol-gel approach to synthesize a NaO-BO-SiO ternary system vitrified bond powder and employs a molding and crushing method, which offers a lower technological barrier and reduced preparation costs, for the production of abrasive particles subsequently fabricating corundum stacked abrasives. Upon setting the binder composition to a molar ratio of n(SiO):n(BO):n(NaO) = 65:23:12, it was observed that the crystallization within the glass matrix was minimized and the optimal sintering temperature for the synthesized laminate abrasive to be sustained at 820 °C. At the aforementioned temperature, the binder melt is capable of flowing uniformly amongst the abrasive granules, thereby ensuring a robust encapsulation of the particles. The average single particle compressive strength of the prepared corundum stacked abrasive with a grain size of forty mesh can reach the highest of all composition points at 28.56 N and the average single particle compressive strength of the prepared diamond stacked abrasive is 28.14 N.

摘要

目前,溶胶-凝胶技术被用于合成高性能的玻璃化结合剂;然而,其在叠层磨具制造中的应用尚未得到充分探索。此外,用于生产叠层磨具磨粒的方法在技术上具有挑战性且成本高昂,这阻碍了它们在实际工业中的应用。因此,本研究利用溶胶-凝胶法合成了一种NaO-BO-SiO三元体系玻璃化结合剂粉末,并采用成型和破碎方法(该方法具有较低的技术壁垒和降低的制备成本)来生产磨粒,随后制造刚玉叠层磨具。当将粘结剂组成设定为n(SiO):n(BO):n(NaO) = 65:23:12的摩尔比时,观察到玻璃基质内的结晶最小化,并且合成的叠层磨具的最佳烧结温度维持在820℃。在上述温度下,粘结剂熔体能够在磨粒之间均匀流动,从而确保对颗粒的牢固包裹。制备的粒度为四十目的刚玉叠层磨具的平均单颗粒抗压强度在所有组成点中最高,可达28.56 N,制备的金刚石叠层磨具的平均单颗粒抗压强度为28.14 N。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2558/11050813/ab8f0b87f6ac/materials-17-01799-g001.jpg

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