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微生物诱导碳酸钙沉淀处理铅锌尾矿砂替代砂作为筑堤材料的无侧限抗压强度及环境影响分析

Analysis of unconfined compressive strength and environmental impact of MICP-treated lead-zinc tailings sand instead of sand as embankment material.

作者信息

Yang Zhenhua, Liu Longkang, Dong Yanrong, Liu Xiaoshuai, Wang Xuezeng

机构信息

College of Mining, Liaoning Technical University, Fuxin, China.

College of Mining, Liaoning Technical University, Fuxin, China.

出版信息

Sci Total Environ. 2024 Jun 25;931:172809. doi: 10.1016/j.scitotenv.2024.172809. Epub 2024 Apr 26.

DOI:10.1016/j.scitotenv.2024.172809
PMID:38679087
Abstract

Tailings can be used as embankment materials instead of sand. However, they contain large amounts of heavy metal pollutants, which can lead to groundwater pollution. In this study, (lead-zinc) Pb-Zn tailings with five particle sizes and Sporosarcina pasteurii were used as test materials. Combined with the unconfined compressive strength (UCS) and leaching of heavy metal pollutants from Pb-Zn tailings, the feasibility of applying microbial induced carbonate precipitation (MICP)-treated Pb-Zn tailings to embankment materials was analysed from the perspective of strength and environmental performance. The results showed that the UCS and carbonate content of the specimens made of Pb-Zn tailings treated using MICP decreased with a decrease in the number of Pb-Zn tailing particles. The pH value of the leaching solution after MICP treatment of Pb-Zn tailings sand was stable at 7.83-8.03, and the fixation rate of metal ions was 90.28 %-100 %. FTIR, X-ray diffraction, scanning electron microscopy, and energy-dispersive spectroscopy tests showed that after the Pb-Zn tailings with particle sizes less than 100 mesh were treated using MICP, the number of carbonate crystals, crystal uniformity, and crystal overlap on the surface of the sample were considerably higher than those of the tailings with particle sizes greater than 250 mesh. The compressive strength and environmental performance of Pb-Zn tailings with particle sizes less than 100 mesh treated using MICP are good, and they are more suitable for embankment materials.

摘要

尾矿可替代沙子用作筑堤材料。然而,它们含有大量重金属污染物,可能导致地下水污染。在本研究中,选用了五种粒径的(铅锌)Pb-Zn尾矿和巴氏芽孢杆菌作为试验材料。结合Pb-Zn尾矿的无侧限抗压强度(UCS)和重金属污染物浸出情况,从强度和环境性能角度分析了采用微生物诱导碳酸盐沉淀(MICP)处理的Pb-Zn尾矿用于筑堤材料的可行性。结果表明,采用MICP处理的Pb-Zn尾矿制成的试样的UCS和碳酸盐含量随Pb-Zn尾矿颗粒数量的减少而降低。对Pb-Zn尾矿砂进行MICP处理后,浸出液的pH值稳定在7.83 - 8.03,金属离子固定率为90.28% - 100%。傅里叶变换红外光谱(FTIR)、X射线衍射、扫描电子显微镜和能谱测试表明,对粒径小于100目的Pb-Zn尾矿进行MICP处理后,样品表面的碳酸盐晶体数量、晶体均匀性和晶体重叠程度均显著高于粒径大于250目的尾矿。采用MICP处理的粒径小于100目的Pb-Zn尾矿的抗压强度和环境性能良好,更适合用作筑堤材料。

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