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活性炭和吐温80增强TiO活性位点电极在电容去离子技术中提高脱盐效率及探索性应用的优化

Optimization of Desalination Efficiency and Exploratory Applications of TiO Active Site Electrode Enhanced by Activated Carbon and Tween 80 in Capacitive Deionization Technology.

作者信息

Liu Xiangzhi, Zhao Xiaolong

机构信息

College of Chemical Engineering, Shandong Institute of Petroleum and Chemical Technology, Dongying 257000, China.

College of Engineering, China University of Petroleum-Beijing AT Karamay, Karamay 834000, China.

出版信息

ACS Omega. 2024 Apr 13;9(16):18249-18259. doi: 10.1021/acsomega.3c10498. eCollection 2024 Apr 23.

DOI:10.1021/acsomega.3c10498
PMID:38680309
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11044207/
Abstract

Capacitive deionization (CDI) is an emerging desalination technology for seawater desalination. The development of high-desalination and long-life electrode materials is a research focus in the global water treatment field. In this experiment, Tween T80 was used as a surface activator, and a modified electrode was prepared by facilitating the deposition of TiO active sites onto the surface of activated carbon through a sol-gel/hydrothermal two-step synthesis strategy. The morphology and specific surface area of the composite material were analyzed through scanning electron microscopy, specific surface area measurements, and contact angle tests. The results indicated that the sol-gel/hydrothermal two-step synthesis strategy played a crucial role in the homogeneous combination and performance enhancement of the composite material. Under constant voltage mode, when the working voltage was 1.2 V, the desalination capacity of this composite material in a NaCl solution with an initial conductivity of 3000 μS·cm reached 23.8 mg·g (26% higher than materials prepared by conventional sol-gel methods). After 150 cycles, the capacity retention rate was 78%, and the retention capacity was significant (87%). Overall, the results demonstrate the potential of the sol-gel/hydrothermal two-step synthesis strategy in preparing high-performance CDI electrode materials. The modified electrode prepared using this method offers enhanced desalination capacity and durability, making it a promising candidate for seawater desalination and other water treatment applications.

摘要

电容去离子化(CDI)是一种新兴的用于海水淡化的脱盐技术。开发高脱盐率和长寿命的电极材料是全球水处理领域的一个研究重点。在本实验中,吐温T80用作表面活性剂,通过溶胶 - 凝胶/水热两步合成策略促进TiO活性位点沉积到活性炭表面来制备改性电极。通过扫描电子显微镜、比表面积测量和接触角测试分析了复合材料的形貌和比表面积。结果表明,溶胶 - 凝胶/水热两步合成策略在复合材料的均匀结合和性能提升中起关键作用。在恒压模式下,当工作电压为1.2 V时,这种复合材料在初始电导率为3000 μS·cm的NaCl溶液中的脱盐容量达到23.8 mg·g(比传统溶胶 - 凝胶法制备的材料高26%)。经过150次循环后,容量保持率为78%,保留容量显著(87%)。总体而言,结果证明了溶胶 - 凝胶/水热两步合成策略在制备高性能CDI电极材料方面的潜力。使用该方法制备的改性电极具有增强的脱盐能力和耐久性,使其成为海水淡化及其他水处理应用的有前途的候选材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ab9/11044207/7a2ee0e7235b/ao3c10498_0008.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ab9/11044207/7a2ee0e7235b/ao3c10498_0008.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ab9/11044207/4e0d011ef0a6/ao3c10498_0002.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ab9/11044207/24c8aadd5f7e/ao3c10498_0004.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ab9/11044207/862204e2fa87/ao3c10498_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ab9/11044207/ee49588a965c/ao3c10498_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ab9/11044207/7a2ee0e7235b/ao3c10498_0008.jpg

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