Effects of Alkali Activation of the Cotton Straw Biochar on the Adsorption Performance for Cd.

In this study, a single factor exploration method was adopted to optimize the cotton shell-based activated carbon adsorption reaction time, temperature, pH value, initial concentration of cadmium ion, and other conditions. The experimental results showed that under the conditions of Cd solution pH = 8, initial concentration of 100 mg/L, adsorption reaction time of 180 min, adsorption temperature of 45 °C, cotton shell-based activated carbon dosage of about 0.1 g, the removal rate of Cd was 94.03%, the adsorption capacity was 51.95 mg/g, and the error was only 0.05%. The adsorption kinetic analysis of this study conforms to the quasi-second-order kinetic model, the adsorption isotherm analysis conforms to the Langmuir adsorption isothermal model, and the Gibbs free energy of the adsorption process is negative; the above simulation analysis also proves the spontaneity and feasibility of the adsorption process.