Qian Nina, Hu Jun, Huang Shuai, Liu Zhiyang, Wang Meng, Keller Patrick, Yang Hong
School of Chemistry and Chemical Engineering, State Key Laboratory of Digital Medical Engineering, Southeast University, Nanjing, Jiangsu Province, 211189, China.
Institut Curie, Centre De Recherche, CNRS UMR 168, Université Pierre et Marie Curie, 26 rue d'Ulm, 75248, Paris Cedex 05, France.
Angew Chem Int Ed Engl. 2024 Jul 15;63(29):e202406534. doi: 10.1002/anie.202406534. Epub 2024 Jun 11.
Stimuli-responsive patterned photonic actuators, characterized by their patterned nano/microscale structures and capacity to demonstrate synergistic color changes and shape morphing in response to external stimuli, have attracted intense scientific attention. However, traditional patterned photonic actuator systems still face limitations such as cumbersome and time-consuming preparation processes and small-scale deformations. Herein, we introduce a facile approach involving an athermal embossing technique to rapidly fabricate patterned photonic actuators based on near-infrared (NIR) light-responsive liquid crystal elastomers. The resulting patterned photonic actuators demonstrate remarkable features, including brilliant angle-dependent structural color, complex three-dimensional actuation, and good color durability under NIR light stimulation. As illustrative demonstrations of the proof-of-concept, we fabricate two light-fuelled patterned photonic soft actuators: a butterfly-inspired actuator that can produce wing-flapping dynamic changes in structural color, and an origami crane-shaped actuator with shape memory, structural color information storage, and dynamic display properties. This strategy provides distinct insights into the design and fabrication of various patterned photonic soft robotic devices and intelligent actuators.
刺激响应型图案化光子致动器,其特征在于具有图案化的纳米/微米级结构以及能够响应外部刺激而展现出协同颜色变化和形状变形的能力,已引起了科学界的广泛关注。然而,传统的图案化光子致动器系统仍然面临诸如制备过程繁琐且耗时以及小规模变形等限制。在此,我们介绍一种简便的方法,该方法涉及一种无热压花技术,用于基于近红外(NIR)光响应液晶弹性体快速制造图案化光子致动器。所得的图案化光子致动器展现出显著的特性,包括出色的角度依赖性结构颜色、复杂的三维致动以及在近红外光刺激下良好的颜色耐久性。作为概念验证的示例演示,我们制造了两种光驱动的图案化光子软致动器:一种受蝴蝶启发的致动器,它能够产生翅膀拍打时结构颜色的动态变化;以及一种具有形状记忆、结构颜色信息存储和动态显示特性的折纸鹤形状的致动器。该策略为各种图案化光子软机器人设备和智能致动器的设计与制造提供了独特的见解。