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用于无辅助太阳能水分解的纳米结构BiVO/NiOOH/FeOOH-CuO/CuO/TiO串联电池的光电化学性能

Photoelectrochemical performance of a nanostructured BiVO/NiOOH/FeOOH-CuO/CuO/TiO tandem cell for unassisted solar water splitting.

作者信息

Sitaaraman S R, Grace A Nirmala, Zhu Jiefang, Sellappan Raja

机构信息

Centre for Nanotechnology Research, Vellore Institute of Technology Vellore India-632014

Department of Electrical and Electronics Engineering, SRM Institute of Science and Technology Ramapuram Chennai India-600089.

出版信息

Nanoscale Adv. 2024 Mar 19;6(9):2407-2418. doi: 10.1039/d4na00088a. eCollection 2024 Apr 30.

DOI:10.1039/d4na00088a
PMID:38694471
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11059491/
Abstract

An unassisted solar water splitting tandem cell is fabricated using FeOOH/NiOOH-coated BiVO nanostructures as a photoanode and a TiO-protected heterojunction CuO/CuO thin film as a photocathode. The individual photoelectrochemical (PEC) performance of the nanostructured BiVO/NiOOH/FeOOH photoanode produces a photocurrent of 2.05 mA cm at 1.23 V RHE, while the CuO/CuO/TiO photocathode delivers -1.61 mA cm at 0 V RHE under an AM 1.5 filtered illumination of 100 mW cm. The operating point of tandem cell photocurrent is found to be 0.273 mA cm at 0.56 V RHE. From two-electrode linear sweep voltammetry, the tandem cell (BiVO/NiOOH/FeOOH-CuO/CuO/TiO) delivers an unassisted current density of 0.201 mA cm at 0 V. The chronoamperometry test further demonstrates the stable nature of the tandem cell, which retains a current density of 0.187 mA cm during a testing duration of 3000 seconds. The proposed tandem cell provides optimized solutions to designing a cost-effective and stable solar water splitting system for the fulfillment of the future energy needs.

摘要

采用涂覆有FeOOH/NiOOH的BiVO纳米结构作为光阳极，以及TiO保护的异质结CuO/CuO薄膜作为光阴极，制备了一种无辅助的太阳能水分解串联电池。纳米结构的BiVO/NiOOH/FeOOH光阳极的单个光电化学（PEC）性能在1.23 V RHE下产生2.05 mA cm²的光电流，而CuO/CuO/TiO光阴极在100 mW cm²的AM 1.5滤光光照下，在0 V RHE下提供-1.61 mA cm²的电流。发现串联电池光电流的工作点在0.56 V RHE下为0.273 mA cm²。通过两电极线性扫描伏安法，串联电池（BiVO/NiOOH/FeOOH-CuO/CuO/TiO）在0 V时提供0.201 mA cm²的无辅助电流密度。计时电流法测试进一步证明了串联电池的稳定性，在3000秒的测试持续时间内，其电流密度保持在0.187 mA cm²。所提出的串联电池为设计一种经济高效且稳定的太阳能水分解系统以满足未来能源需求提供了优化解决方案。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eb87/11059491/7fcc6f39c5aa/d4na00088a-f11.jpg
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Nat Commun. 2023 Jun 26;14(1):3797. doi: 10.1038/s41467-023-39290-y.
2
Photoelectrochemical performance of a spin coated TiO protected BiVO-CuO thin film tandem cell for unassisted solar water splitting.用于无辅助太阳能水分解的旋涂TiO保护的BiVO-CuO薄膜串联电池的光电化学性能。
RSC Adv. 2022 Nov 2;12(48):31380-31391. doi: 10.1039/d2ra05774c. eCollection 2022 Oct 27.
3
Characterization of CuO/CuO heterostructure photocathode by tailoring CuO thickness for photoelectrochemical water splitting.
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RSC Adv. 2022 Jan 20;12(5):2632-2640. doi: 10.1039/d1ra08863g. eCollection 2022 Jan 18.
4
Assessment of a W:BiVO-CuBiOTandem Photoelectrochemical Cell for Overall Solar Water Splitting.用于整体太阳能水分解的W:BiVO-CuBiO串联光电化学电池的评估
ACS Appl Mater Interfaces. 2020 Mar 25;12(12):13959-13970. doi: 10.1021/acsami.0c00696. Epub 2020 Mar 10.
5
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Faraday Discuss. 2019 Jul 4;215(0):297-312. doi: 10.1039/c8fd00183a.
6
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ACS Appl Mater Interfaces. 2018 Apr 18;10(15):12639-12650. doi: 10.1021/acsami.8b00304. Epub 2018 Apr 9.
7
Room-Temperature Processing of TiO Electron Transporting Layer for Perovskite Solar Cells.用于钙钛矿太阳能电池的TiO电子传输层的室温处理
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8
Photoelectrochemical devices for solar water splitting - materials and challenges.用于太阳能水分解的光电化学器件-材料与挑战。
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9
A Dye-Sensitized Photoelectrochemical Tandem Cell for Light Driven Hydrogen Production from Water.染料敏化光电化学串联电池用于光驱动水分解制氢。
J Am Chem Soc. 2016 Dec 28;138(51):16745-16753. doi: 10.1021/jacs.6b10699. Epub 2016 Dec 15.
10
CuO/CuO Bilayered Composite as a High-Efficiency Photocathode for Photoelectrochemical Hydrogen Evolution Reaction.氧化铜/氧化铜双层复合材料作为用于光电化学析氢反应的高效光阴极
Sci Rep. 2016 Oct 17;6:35158. doi: 10.1038/srep35158.