Suvorova Veronika, Volodko Sergey, Suvorov Dmitrii, Chernyshikhin Stanislav, Nepapushev Andrey, Korol Artem, Volkova Lidiya, Sokolov Pavel, Khort Alexander, Moskovskikh Dmitry
University of Science and Technology MISIS, Moscow, Russia.
Institute of Nanotechnology of Microelectronics of the Russian Academy of Sciences, Moscow, Russia.
Sci Rep. 2024 May 2;14(1):10152. doi: 10.1038/s41598-024-58614-6.
Aluminum matrix composites (AMCs), incorporating Zirconium Nitride (ZrN) as reinforcing additives, demonstrate immense promise for applications in aerospace, automotive, and power generation due to their unique combination of low density, superior mechanical properties, and excellent thermal/electrical conductivity. This study explores the influence of ZrN reinforcement on the microstructure and mechanical properties of AlSi10Mg metal-matrix composites. Utilizing high-energy ball milling (HEBM) and spark-plasma sintering (SPS), ZrN/AlSi10Mg composites were synthesized, achieving nearly full density with uniform ZrN distribution, while phase and chemical transformations were not observed in the bulk composites. The addition of ZrN resulted in a notable increase in hardness of 237% (182 ± 8 HV), elastic modulus of 56% (114 ± 3 GPa), compressive and tensile strength of 183% (565 ± 15 GPa), and 125% (387 ± 9 GPa), respectively, for composites containing 30% ZrN, compared to the non-reinforced alloy. Experimentally determined coefficients of thermal expansion (CTEs) for composites with 10%, 20%, and 30% ZrN content were 19.8 × 10 °C, 19.1 × 10 °C, and 18 × 10 °C, respectively, which well relates to Schapery's model. These findings contribute to understanding the synthesis, mechanical behavior, and thermal properties of ZrN/AlSi10Mg composites, demonstrating their potential for diverse engineering applications.
以氮化锆(ZrN)作为增强添加剂的铝基复合材料(AMC),由于其低密度、优异的机械性能以及出色的热/电导率等独特组合,在航空航天、汽车和发电领域的应用中展现出巨大潜力。本研究探讨了ZrN增强相对AlSi10Mg金属基复合材料微观结构和机械性能的影响。通过高能球磨(HEBM)和放电等离子烧结(SPS)合成了ZrN/AlSi10Mg复合材料,实现了接近全密度且ZrN分布均匀,同时在块状复合材料中未观察到相和化学转变。与未增强的合金相比,添加ZrN后,含30%ZrN的复合材料硬度显著提高237%(182±8 HV),弹性模量提高56%(114±3 GPa),压缩强度和拉伸强度分别提高183%(565±15 GPa)和125%(387±9 GPa)。含10%、20%和30%ZrN的复合材料的实验测定热膨胀系数(CTE)分别为19.8×10℃、19.1×10℃和18×10℃,这与沙佩里模型吻合良好。这些发现有助于理解ZrN/AlSi10Mg复合材料的合成、力学行为和热性能,证明了它们在各种工程应用中的潜力。