School of Civil Engineering and Architecture, University of Jinan, Jinan, China.
Jinan Municipal Engineering Design &Research Institute (Group) CO., LTD., Jinan, China.
Water Environ Res. 2024 May;96(5):e11032. doi: 10.1002/wer.11032.
In recent years, ceramic membranes have been increasingly used in membrane bioreactors (MBRs). However, membrane fouling was still the core issue restricting the large-scale engineering application of ceramic MBRs. As a novel and alternative technology, ultrasonic could be used to control membrane fouling. This research focused on the efficiency and mechanism of ultrasonic controlling membrane fouling in ceramic MBRs. The results showed that ultrasonic reduced the sludge concentration in MBR, and the average particle size of sludge was always in a high range. The sludge activity of the system was stable at 6-9 (mg O·(g MLSS·h)), indicating that ultrasonic did not destroy the activity of microorganisms in the system. The extracellular polymer substance (EPS) of the ultrasonic group was slightly higher than that of the control group, while the soluble microbial product (SMP) content was relatively stable. The ceramic membrane of the ultrasonic group has a partial retention effect on the organic components. The application of ultrasonic slowed down the decrease of the hydrophilicity of the ceramic membrane. The main pollutants on the membrane surface exist in the form of aromatic and heteroaromatic rings, alkynes, and so forth. Ultrasonic removes the amide substances from the membrane surface. Membrane fouling resistance is mainly due to membrane pore blockage, accounting for 75.53%. PRACTITIONER POINTS: Enrich the research on the mechanism of ultrasonic technology in membrane fouling control. The MBR can still operate normally with ultrasonic applied. The time for the ceramic membrane to reach the fouling end point is 2.4 times that without ultrasonic. The main cause of membrane fouling was pore blocking, accounting for 75.53%.
近年来,陶瓷膜在膜生物反应器(MBR)中得到了越来越多的应用。然而,膜污染仍然是限制陶瓷 MBR 大规模工程应用的核心问题。超声作为一种新颖的替代技术,可以用于控制膜污染。本研究聚焦于超声控制陶瓷 MBR 中膜污染的效率和机制。结果表明,超声降低了 MBR 中的污泥浓度,且污泥的平均粒径始终处于较高范围。系统中污泥的活性稳定在 6-9(mg O·(g MLSS·h)),表明超声并未破坏系统中微生物的活性。超声组的胞外聚合物(EPS)略高于对照组,而可溶性微生物产物(SMP)含量相对稳定。超声对有机成分具有部分截留作用。超声减缓了陶瓷膜亲水性的降低。超声组的陶瓷膜对有机污染物具有一定的截留效果。膜表面的主要污染物以芳香族和杂环、炔烃等形式存在。超声从膜表面去除了酰胺类物质。膜污染阻力主要是由于膜孔堵塞造成的,占 75.53%。
丰富超声技术在膜污染控制中作用机制的研究。应用超声后,MBR 仍能正常运行。与未施加超声相比,陶瓷膜达到污染终点的时间延长了 2.4 倍。膜污染的主要原因是孔径堵塞,占 75.53%。