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基于丙烯酸/丙烯酰胺共聚物和酸改性凹凸棒土的高吸水性复合材料的溶胀行为

Swelling behaviors of superabsorbent composites based on acrylic acid/acrylamide copolymer and acid-modified attapulgite.

作者信息

Ren Hanru, Ren Jun, Tao Ling, Ren Xuechang

机构信息

School of Environmental and Municipal Engineering, Lanzhou Jiaotong University Lanzhou 730070 P. R. China

Gansu Hanxing Environmental Protection Co. Ltd Lanzhou 730070 China.

出版信息

RSC Adv. 2024 May 7;14(21):14758-14766. doi: 10.1039/d4ra01021c. eCollection 2024 May 2.

DOI:10.1039/d4ra01021c
PMID:38716095
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11074873/
Abstract

The swelling behaviors and water retention of superabsorbent materials prepared from acrylic acid/acrylamide copolymer and acid-modified attapulgite under ultrasonic treatment and different pH conditions were investigated. The results demonstrated that a suitable amount of attapulgite can effectively improve the absorption capacity. The superabsorbent achieved the highest absorptions of 1257.54 g g and 209.45 g g in distilled water and a 0.9 wt% NaCl solution, and a higher water absorbency occurred over a wide pH range of 5-9 when the ultrasonic power was 200 W, and the attapulgite content was 10%. Addition of attapulgite could significantly increase the water absorption and retention of this kind of material, which can be applied as a sand-fixing material.

摘要

研究了在超声处理和不同pH条件下,由丙烯酸/丙烯酰胺共聚物和酸改性凹凸棒石制备的高吸水性材料的溶胀行为和保水性能。结果表明,适量的凹凸棒石能有效提高其吸收能力。该高吸水性材料在蒸馏水和0.9 wt% NaCl溶液中的最高吸水量分别为1257.54 g/g和209.45 g/g,当超声功率为200 W且凹凸棒石含量为10%时,在5-9的较宽pH范围内具有较高的吸水性。添加凹凸棒石可显著提高这类材料的吸水和保水能力,其可作为固沙材料应用。

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本文引用的文献

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Superabsorbent nanocomposite from sugarcane bagasse, chitin and clay: Synthesis, characterization and swelling behaviour.由甘蔗渣、壳聚糖和粘土制成的高吸水性纳米复合材料:合成、表征和溶胀行为。
Carbohydr Polym. 2018 Aug 1;193:281-288. doi: 10.1016/j.carbpol.2018.04.006. Epub 2018 Apr 3.
2
Effect of surfactant on porosity and swelling behaviors of guar gum-g-poly(sodium acrylate-co-styrene)/attapulgite superabsorbent hydrogels.表面活性剂对瓜尔胶-g-聚(丙烯酸钠-co-苯乙烯)/凹凸棒土超吸水性水凝胶的孔隙率和溶胀行为的影响。
Colloids Surf B Biointerfaces. 2011 Nov 1;88(1):279-86. doi: 10.1016/j.colsurfb.2011.07.002. Epub 2011 Jul 12.
3
Utilization of starch and clay for the preparation of superabsorbent composite.
利用淀粉和黏土制备高吸水性复合材料。
Bioresour Technol. 2007 Jan;98(2):327-32. doi: 10.1016/j.biortech.2005.12.026. Epub 2006 Feb 21.