• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

4-（1-2,3-二氢-萘并-[1,8-][1,3,2]二氮杂硼宁-2-基）-1-乙基吡啶-1-鎓碘化物

4-(1-2,3-Dihydro-naphtho-[1,8-][1,3,2]di-aza-borinin-2-yl)-1-ethylpyridin-1-ium iodide.

作者信息

Hashimoto Shu, Okuno Tsunehisa

机构信息

Department of Systems Engineering, Wakayama University, Sakaedani, Wakayama, 640-8510, Japan.

出版信息

IUCrdata. 2024 Apr 26;9(Pt 4):x240362. doi: 10.1107/S2414314624003626. eCollection 2024 Apr.

DOI:10.1107/S2414314624003626
PMID:38720995
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11074540/
Abstract

The title compound, CHBNI, is a type of di-aza-borinane featuring substitution at the 1, 2, and 3 positions of the nitro-gen-boron six-membered heterocycle. The organic mol-ecule has a planar structure, the dihedral angle between the pyridyl ring and the fused ring system being 3.46 (4)°. In the crystal, mol-ecules are stacked in a head-to-tail manner. The iodide ion makes close contacts with three organic mol-ecules and supports the alternating stack.

摘要

标题化合物CHBNI是一种二氮杂硼烷，其在氮硼六元杂环的1、2和3位有取代基。有机分子具有平面结构，吡啶环与稠环体系之间的二面角为3.46 (4)°。在晶体中，分子以头对尾的方式堆积。碘离子与三个有机分子紧密接触并支撑交替堆积。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d064/11074540/0f2d50c8889c/x-09-x240362-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d064/11074540/afeda4726815/x-09-x240362-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d064/11074540/0f2d50c8889c/x-09-x240362-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d064/11074540/afeda4726815/x-09-x240362-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d064/11074540/0f2d50c8889c/x-09-x240362-fig2.jpg

相似文献

1
4-(1-2,3-Dihydro-naphtho-[1,8-][1,3,2]di-aza-borinin-2-yl)-1-ethylpyridin-1-ium iodide.4-（1-2,3-二氢-萘并-[1,8-][1,3,2]二氮杂硼宁-2-基）-1-乙基吡啶-1-鎓碘化物
IUCrdata. 2024 Apr 26;9(Pt 4):x240362. doi: 10.1107/S2414314624003626. eCollection 2024 Apr.
2
4-(1-2,3-Dihydronaphtho-[1,8-][1,3,2]di-aza-borinin-2-yl)-1-ethylpyridin-1-ium iodide monohydrate.4-（1-2,3-二氢萘并-[1,8-][1,3,2]二氮杂硼硼烷-2-基）-1-乙基吡啶-1-鎓碘化物一水合物
IUCrdata. 2024 Apr 26;9(Pt 4):x240369. doi: 10.1107/S2414314624003699. eCollection 2024 Apr.
3
2-(Pyridin-4-yl)-2,3-di-hydro-1-naphtho-[1,8-][1,3,2]di-aza-borinine.2 -（吡啶 - 4 - 基）- 2,3 - 二氢 - 1 - 萘并[1,8 - ][1,3,2]二氮杂硼宁
IUCrdata. 2024 Jun 28;9(Pt 6):x240615. doi: 10.1107/S2414314624006151. eCollection 2024 Jun.
4
2-[4-(Methyl-sulfan-yl)phen-yl]naphtho[1,8-de][1,3,2]diaza-borinane.2-[4-(甲硫基)苯基]萘并[1,8-de][1,3,2]二氮杂硼烷
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1338. doi: 10.1107/S1600536811014693. Epub 2011 May 7.
5
2-(4-Chloro-phen-yl)naphtho-[1,8-de][1,3,2]diaza-borinane.2-（4-氯苯基）萘并-[1,8-de][1,3,2]二氮杂硼烷
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o1873. doi: 10.1107/S1600536811025487. Epub 2011 Jul 2.
6
2-Phenyl-naphtho-[1,8-de][1,3,2]diaza-borinane.2-苯基-萘并-[1,8-de][1,3,2]二氮杂硼烷
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o1995. doi: 10.1107/S1600536811026985. Epub 2011 Jul 9.
7
Co-crystallization of a neutral mol-ecule and its zwitterionic tautomer: structure and Hirshfeld surface analysis of 5-methyl-4-(5-methyl-1-pyrazol-3-yl)-2-phenyl-2,3-di-hydro-1-pyrazol-3-one 5-methyl-4-(5-methyl-1-pyrazol-2-ium-3-yl)-3-oxo-2-phenyl-2,3-di-hydro-1-pyrazol-1-ide monohydrate.一种中性分子与其两性离子互变异构体的共结晶：5-甲基-4-(5-甲基-1-吡唑-3-基)-2-苯基-2,3-二氢-1-吡唑-3-酮5-甲基-4-(5-甲基-1-吡唑-2-鎓-3-基)-3-氧代-2-苯基-2,3-二氢-1-吡唑-1-化物一水合物的结构和 Hirshfeld 表面分析
Acta Crystallogr E Crystallogr Commun. 2019 Apr 5;75(Pt 5):565-570. doi: 10.1107/S2056989019004389. eCollection 2019 May 1.
8
10-{4-[(2-Hy-droxy-benzyl-idene)amino]-phen-yl}-5,5-di-fluoro-1,3,7,9-tetra-methyl-5H-di-pyrrolo-[1,2-c:2',1'-f][1,3,2]di-aza-borinin-4-ium-5-uide.10-{4-[(2-羟基苄叉基)氨基]苯基}-5,5-二氟-1,3,7,9-四甲基-5H-二吡咯并-[1,2-c:2',1'-f][1,3,2]二氮杂硼宁-4-鎓-5-化物
Acta Crystallogr Sect E Struct Rep Online. 2013 Jun 12;69(Pt 7):o1072. doi: 10.1107/S1600536813015523. eCollection 2013.
9
Crystal structure of 1,3-di--butyl-2-chloro-1,3,2-di-aza-phospho-rinane - a saturated six-membered phospho-rus nitro-gen heterocycle with a partially flattened chair conformation and a long P-Cl bond.1,3 - 二 - 丁基 - 2 - 氯 - 1,3,2 - 二氮磷杂环己烷的晶体结构——一种具有部分扁平椅式构象和长P - Cl键的饱和六元磷氮杂环化合物。
Acta Crystallogr E Crystallogr Commun. 2019 Apr 2;75(Pt 5):552-556. doi: 10.1107/S2056989019004195. eCollection 2019 May 1.
10
6,6'-Di-nitro-1,1'-(ethane-1,2-di-yl)di(1H-indazole).6,6'-二硝基-1,1'-(乙烷-1,2-二基)二(1H-吲唑)
Acta Crystallogr Sect E Struct Rep Online. 2014 Mar 5;70(Pt 4):o390. doi: 10.1107/S1600536814004516. eCollection 2014 Apr 1.

引用本文的文献

1
2-(Pyridin-4-yl)-2,3-di-hydro-1-naphtho-[1,8-][1,3,2]di-aza-borinine.2 -（吡啶 - 4 - 基）- 2,3 - 二氢 - 1 - 萘并[1,8 - ][1,3,2]二氮杂硼宁
IUCrdata. 2024 Jun 28;9(Pt 6):x240615. doi: 10.1107/S2414314624006151. eCollection 2024 Jun.
2
4-(1-2,3-Dihydronaphtho-[1,8-][1,3,2]di-aza-borinin-2-yl)-1-ethylpyridin-1-ium iodide monohydrate.4-（1-2,3-二氢萘并-[1,8-][1,3,2]二氮杂硼硼烷-2-基）-1-乙基吡啶-1-鎓碘化物一水合物
IUCrdata. 2024 Apr 26;9(Pt 4):x240369. doi: 10.1107/S2414314624003699. eCollection 2024 Apr.

本文引用的文献

1
4-(1-2,3-Dihydronaphtho-[1,8-][1,3,2]di-aza-borinin-2-yl)-1-ethylpyridin-1-ium iodide monohydrate.4-（1-2,3-二氢萘并-[1,8-][1,3,2]二氮杂硼硼烷-2-基）-1-乙基吡啶-1-鎓碘化物一水合物
IUCrdata. 2024 Apr 26;9(Pt 4):x240369. doi: 10.1107/S2414314624003699. eCollection 2024 Apr.
2
MIDA- and TIDA-Boronates Stabilize α-Radicals Through B-N Hyperconjugation.MIDA-硼酸酯和TIDA-硼酸酯通过B-N超共轭作用稳定α-自由基。
Angew Chem Int Ed Engl. 2023 Oct 2;62(40):e202309566. doi: 10.1002/anie.202309566. Epub 2023 Aug 18.
3
2-Phenyl-naphtho-[1,8-de][1,3,2]diaza-borinane.
2-苯基-萘并-[1,8-de][1,3,2]二氮杂硼烷
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o1995. doi: 10.1107/S1600536811026985. Epub 2011 Jul 9.
4
2-(4-Chloro-phen-yl)naphtho-[1,8-de][1,3,2]diaza-borinane.2-（4-氯苯基）萘并-[1,8-de][1,3,2]二氮杂硼烷
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o1873. doi: 10.1107/S1600536811025487. Epub 2011 Jul 2.