Hashimoto Shu, Okuno Tsunehisa
Department of Systems Engineering, Wakayama University, Sakaedani, Wakayama, 640-8510, Japan.
IUCrdata. 2024 Apr 26;9(Pt 4):x240362. doi: 10.1107/S2414314624003626. eCollection 2024 Apr.
The title compound, CHBNI, is a type of di-aza-borinane featuring substitution at the 1, 2, and 3 positions of the nitro-gen-boron six-membered heterocycle. The organic mol-ecule has a planar structure, the dihedral angle between the pyridyl ring and the fused ring system being 3.46 (4)°. In the crystal, mol-ecules are stacked in a head-to-tail manner. The iodide ion makes close contacts with three organic mol-ecules and supports the alternating stack.
标题化合物CHBNI是一种二氮杂硼烷,其在氮硼六元杂环的1、2和3位有取代基。有机分子具有平面结构,吡啶环与稠环体系之间的二面角为3.46 (4)°。在晶体中,分子以头对尾的方式堆积。碘离子与三个有机分子紧密接触并支撑交替堆积。