Jovanovic Dragana, Poliyodath Mohanan Meghana, Huber Stefan M
Faculty of Chemistry and Biochemistry, Ruhr-University Bochum, Universitätsstraße 150, 44801, Bochum, Germany.
Angew Chem Int Ed Engl. 2024 Jul 29;63(31):e202404823. doi: 10.1002/anie.202404823. Epub 2024 Jul 2.
The use of noncovalent interactions based on electrophilic halogen, chalcogen, pnictogen, or tetrel centers in organocatalysis has gained noticeable attention. Herein, we provide an overview on the most important developments in the last years with a clear focus on experimental studies and on catalysts which act via such non-transient interactions.
基于亲电卤素、硫族元素、氮族元素或碳族元素中心的非共价相互作用在有机催化中的应用已受到显著关注。在此,我们概述了过去几年中最重要的进展,重点明确放在实验研究以及通过此类非瞬时相互作用起作用的催化剂上。