Liu Jin, Luo Lida, Xu Jiali, Zhu Xiaoxu, Shi Guoying, Wang Qingwei
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China.
Engineering Research Center of Advanced Glass Manufacturing Technology, Ministry of Education, Donghua University, Shanghai 201620, China.
Materials (Basel). 2024 Apr 26;17(9):2043. doi: 10.3390/ma17092043.
Lunar mare basalt is recognized as an important in situ resource on the lunar surface. However, the significant compositional variability of lunar mare basalts introduces uncertainties concerning the potential for their use in fabricating fibers and composite materials. This study investigates the impact of different components on the fiber-forming capabilities of mare basalts by simulating the compositions of basalts collected from several well-known lunar missions and then preparing simulated lunar mare basalt fibers. Raman spectroscopy is primarily employed for analysis and characterization, using "peak area normalization" to explore the impact of compositional fluctuations in the simulated lunar mare basalts on the glass network structure. The findings indicate that an increase in the Fe content raises the likelihood of basalt fibers crystallizing. Additionally, Fe is shown to substitute for Si and Al in constructing bridging oxygen bonds in the network structure, albeit reducing the overall polymerization of the network. Meanwhile, Fe acts as a network modifier to enhance the mechanical properties of the fibers.
月海玄武岩被认为是月球表面一种重要的原位资源。然而,月海玄武岩显著的成分变异性给其在制造纤维和复合材料方面的应用潜力带来了不确定性。本研究通过模拟从几次著名月球任务中采集的玄武岩成分,然后制备模拟月海玄武岩纤维,来研究不同成分对月海玄武岩成纤能力的影响。拉曼光谱主要用于分析和表征,采用“峰面积归一化”来探究模拟月海玄武岩中成分波动对玻璃网络结构的影响。研究结果表明,铁含量的增加会提高玄武岩纤维结晶的可能性。此外,研究表明铁在构建网络结构中的桥氧键时会替代硅和铝,尽管这会降低网络的整体聚合度。同时,铁作为网络改性剂可增强纤维的机械性能。