Synthesis and properties of an -doped aromatic belt.
作者信息
Han Ying, Guo Wei-Chen, Du Xu-Sheng, Chen Chuan-Feng
机构信息
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
University of Chinese Academy of Sciences, Beijing 100049, China.
出版信息
Chem Commun (Camb). 2024 May 28;60(44):5719-5722. doi: 10.1039/d4cc01667j.
PMID:38742271
Abstract
A new macrocyclic arene, dibenzofuran[3]arene, was synthesized, which could be conveniently transformed to an -doped aromatic belt with a rigid ring-shaped structure and deep cavity. Moreover, the -doped aromatic belt also showed a high HOMO energy and a narrow HOMO-LUMO gap experimentally and theoretically.
摘要
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