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研究不同热解温度下 Fe 改性污泥生物炭对水中四环素的吸附。

Seeking the adsorption of tetracycline in water by Fe-modified sludge biochar at different pyrolysis temperatures.

机构信息

Henan University of Urban Construction, Henan Key Laboratory of Water Pollution Control and Rehabilitation Technology, Pingdingshan, 467000, People's Republic of China.

School of Civil and Surveying Engineering, Jiangxi University of Science and Technology, Ganzhou, 341000, People's Republic of China.

出版信息

Environ Sci Pollut Res Int. 2024 May;31(25):36702-36715. doi: 10.1007/s11356-024-33631-0. Epub 2024 May 16.

DOI:10.1007/s11356-024-33631-0
PMID:38753232
Abstract

The composite material SBC-Fe-x with sludge and Fe was developed by different calcination temperatures (600, 700, and 800 °C) for the removal of tetracycline (TC). The adsorption rates of SBC-Fe-600, SBC-Fe-700, and SBC-Fe-800 were 77.5%, 89%, and 91%, respectively. Furthermore, the Langmuir model indicated that the maximum adsorption capacity of SBC-Fe-700 (157.93 mg/g) was three times greater than that of SBC-Fe-600. The conclusions were confirmed by a series of characterizations that SBC-Fe-700 showed a larger specific surface area, well-developed pore structure, rich oxygen-containing functional groups and a high degree of graphitization. The results of pH experiments indicated the broad applicability of SBC-Fe-700 for TC adsorption. In addition, SBC-Fe-700 suggested outstanding performance in different water environments. This work produced a feasible adsorbent for the removal of TC, and a new direction for sludge resource utilization was proposed.

摘要

开发了一种由不同煅烧温度(600、700 和 800°C)制备的复合材料 SBC-Fe-x(包含污泥和 Fe),用于去除四环素(TC)。SBC-Fe-600、SBC-Fe-700 和 SBC-Fe-800 的吸附率分别为 77.5%、89%和 91%。此外,Langmuir 模型表明,SBC-Fe-700 的最大吸附容量(157.93 mg/g)是 SBC-Fe-600 的三倍。一系列特性的证实了这一结论,表明 SBC-Fe-700 具有更大的比表面积、发达的孔结构、丰富的含氧官能团和高石墨化程度。pH 值实验结果表明,SBC-Fe-700 对 TC 吸附具有广泛的适用性。此外,SBC-Fe-700 在不同水环境中表现出优异的性能。这项工作为去除 TC 提供了一种可行的吸附剂,并为污泥资源利用提出了新的方向。

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