Liu Pengye, Wang Chang, Zhang Daoyuan, Wang Xiang, Duan Defang, Liu Zhao, Cui Tian
Institute of High Pressure Physics, School of Physical Science and Technology, Ningbo University, Ningbo 315211, People's Republic of China.
State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012, People's Republic of China.
J Phys Condens Matter. 2024 Jun 4;36(35). doi: 10.1088/1361-648X/ad4ccc.
The successful prediction and confirmation of unprecedentedly high-temperature superconductivity in compressed hydrogen-rich hydrides signify a remarkable advancement in the continuous quest for attaining room-temperature superconductivity. The recent studies have established a broad scope for developing binary and ternary hydrides and illustrated correlation between specific hydrogen motifs and high-s under high pressures. The analysis of the microscopic mechanism of superconductivity in hydrides suggests that the high electronic density of states at the Fermi level (E), the large phonon energy scale of the vibration modes and the resulting enhanced electron-phonon coupling are crucial contributors towards the high-phonon-mediated superconductors. The aim of our efforts is to tackle forthcoming challenges associated with elevating theand reducing the stabilization pressures of hydrogen-based superconductors, and offer insights for the future discoveries of room-temperature superconductors. Our present Review offers an overview and analysis of the latest advancements in predicting and experimentally synthesizing various crystal structures, while also exploring strategies to enhance the superconductivity and reducing their stabilization pressures of hydrogen-rich hydrides.
在富氢氢化物中成功预测并证实前所未有的高温超导性,标志着在持续追求室温超导性的征程中取得了显著进展。近期研究为开发二元和三元氢化物开辟了广阔空间,并阐明了在高压下特定氢结构与高超导性之间的关联。对氢化物中超导微观机制的分析表明,费米能级(E)处高的电子态密度、振动模式的大声子能量尺度以及由此增强的电子 - 声子耦合是高 phonon 介导超导性的关键因素。我们努力的目标是应对与提高氢基超导体的超导转变温度和降低其稳定压力相关的未来挑战,并为室温超导体的未来发现提供见解。我们当前的综述概述并分析了预测和实验合成各种晶体结构的最新进展,同时还探索了增强富氢氢化物超导性并降低其稳定压力的策略。