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一种 MAX 相(TiAlC)作为聚乳酸电纺膜在蒸汽发生和太阳能脱盐中的性能增强剂。

A MAX phase (TiAlC) as a performance enhancer for poly(lactic acid) electrospun membranes in steam generation and solar desalination.

机构信息

Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand; Center of Excellence for Innovation in Chemistry (PERCH-CIC), Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand.

Department of Basic Science and Physical Education, Faculty of Science at Sriracha, Kasetsart University Sriracha Campus, Chonburi 20230, Thailand.

出版信息

Int J Biol Macromol. 2024 Jun;270(Pt 2):132380. doi: 10.1016/j.ijbiomac.2024.132380. Epub 2024 May 14.

Abstract

Clean water and sanitation issues motivate researchers to develop water evaporators for freshwater generation. The composite membrane evaporator was electrospun herein based on poly(lactic acid) (PLA) and TiAlC MAX phase as a property enhancer. As a precursor for the MXenes synthesis, the MAX phase has never been explored with PLA for water evaporator potential. Alternative use of the MAX phase can reduce the production cost arising from chemical synthesis. This work explored the potential of the MAX phase as an additive to enhance PLA membrane performance for steam generation and desalination applications. Under the infrared irradiation (∼1.0 kW/m), the mechanically-improved PLA/MAX phase membrane showed an enhanced water evaporation rate of 1.70 kg/m h (93.93 % efficiency), with an approximately 52 % rate increment relative to the PLA membrane. Based on the artificial seawater (3.5 % w/w), the membrane exhibited an evaporation rate of 1.60 kg/m h (87.57 % efficiency). The membrane showed self-floating ability at the air-water interface, excellent thermal stability over the entire operating temperatures, and reusability after repeated cycles. Moreover, the generated freshwater contained exceptionally low cations concentrations, as low as those in potable water. The developed composite membrane also had proved its potential for solar desalination in the water generation field.

摘要

清洁水和卫生问题促使研究人员开发用于淡水生成的水蒸发器。本文基于聚乳酸(PLA)和 TiAlC MAX 相作为性能增强剂,静电纺丝制备了复合膜蒸发器。作为 MXenes 合成的前体,MAX 相从未被探索过用于 PLA 水蒸发器的潜力。MAX 相的替代用途可以降低化学合成带来的生产成本。这项工作探讨了 MAX 相作为添加剂的潜力,以增强 PLA 膜在蒸汽生成和脱盐应用中的性能。在红外辐射(约 1.0kW/m)下,机械性能得到提高的 PLA/MAX 相膜表现出 1.70kg/mh 的增强水蒸发率(93.93%效率),与 PLA 膜相比,蒸发率提高了约 52%。基于人工海水(3.5%w/w),膜的蒸发率为 1.60kg/mh(87.57%效率)。该膜在空气-水界面具有自浮能力,在整个工作温度范围内具有优异的热稳定性,并且在重复循环后具有可重复使用性。此外,所产生的淡水所含阳离子浓度异常低,低至饮用水中的浓度。开发的复合膜还证明了其在水生成领域太阳能淡化方面的潜力。

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