Šćepanović Stefan, Kimouche Amina, Mirković Jovan, Sadiek Gehad, Klamroth Tillmann, Hassanien Abdou
Jozef Stefan Institute, 39 Jamova, 1000, Ljubljana, Slovenia.
Faculty of Sciences, University of Montenegro, 81000, Podgorica, Montenegro.
Sci Rep. 2024 May 21;14(1):11641. doi: 10.1038/s41598-024-62624-9.
Using scanning tunneling microscopy and spectroscopy we demonstrate a revival of magnetism in 7-armchair nanoribbon by unpassivated atoms at the termini. Namely, a pair of intense Kondo resonances emerges at the peripheries of zigzag terminus revealing the many-body screening effects of local magnetic moments. Although Kondo resonance originates from a missing local orbital, it extends to a distance of 2.5 nm along the edge of the ribbon. The results are complemented by density functional theory calculations which suggest a possible coupling between Kondo states despite screening effects of substrate electrons. These findings indicate a possibility to restore intrinsic magnetic ordering in graphene nanoribbon without major structural modifications.
利用扫描隧道显微镜和光谱学,我们证明了在7扶手椅型纳米带中,末端未钝化的原子会使磁性恢复。具体而言,在锯齿形末端的边缘出现了一对强烈的近藤共振,揭示了局域磁矩的多体屏蔽效应。尽管近藤共振源于一个缺失的局域轨道,但它沿着纳米带的边缘延伸了2.5纳米的距离。密度泛函理论计算对这些结果进行了补充,该计算表明,尽管存在衬底电子的屏蔽效应,但近藤态之间仍可能存在耦合。这些发现表明,在不对石墨烯纳米带进行重大结构修改的情况下,恢复其本征磁有序是有可能的。