Ashie Moses D, Kumar Dhananjay, Bastakoti Bishnu Prasad
Department of Chemistry, North Carolina Agricultural and Technical State University, 1601 E. Market St, Greensboro, NC-27411, USA.
Department of Mechanical Engineering, North Carolina Agricultural and Technical State University, 1601 E. Market St, Greensboro, NC-27411, USA.
Chem Rec. 2024 May;24(5):e202400016. doi: 10.1002/tcr.202400016. Epub 2024 May 22.
Hydrogen gas is a prominent focus in pursuing renewable and clean alternative energy sources. The quest for maximizing hydrogen production yield involves the exploration of an ideal photocatalyst and the development of a simple, cost-effective technique for its generation. Iron titanate has garnered attention in this context due to its photocatalytic properties, affordability, and non-toxic nature. Over the years, different synthesis routes, different morphologies, and some modifications of iron titanate have been carried out to improve its photocatalytic performance by enhancing light absorption in the visible region, boosting charge carrier transfer, and decreasing recombination of electrons and holes. The use of iron titanate photocatalyst for hydrogen evolution reaction has seen an upward trend in recent times, and based on available findings, more can be done to improve the performance. This review paper provides a comprehensive overview of the fundamental principles of photocatalysis for hydrogen generation, encompassing the synthesis, morphology, and application of iron titanate-based photocatalysts. The discussion delves into the limitations of current methodologies and present and future perspectives for advancing iron titanate photocatalysts. By addressing these limitations and contemplating future directions, the aim is to enhance the properties of materials fabricated for photocatalytic water splitting.
氢气是追求可再生和清洁替代能源的一个突出重点。为了使氢气产量最大化,人们致力于探索理想的光催化剂,并开发一种简单、经济高效的制备技术。钛酸铁因其光催化性能、价格低廉且无毒的特性,在这一领域受到了关注。多年来,人们通过增强可见光区域的光吸收、促进电荷载流子转移以及减少电子与空穴的复合,对钛酸铁进行了不同的合成路线、不同形态的制备以及一些改性,以提高其光催化性能。近年来,使用钛酸铁光催化剂进行析氢反应呈上升趋势,基于现有研究结果,还有更多工作可做以提高其性能。本文综述全面概述了光催化产氢的基本原理,包括钛酸铁基光催化剂的合成、形态及应用。讨论深入探讨了当前方法的局限性以及推进钛酸铁光催化剂的现状和未来前景。通过解决这些局限性并思考未来方向,旨在增强用于光催化水分解的材料的性能。