Trimethylsilyldiazomethane Disassembly at a Three-Fold Symmetric Iron Site.

The reaction of equimolar trimethylsilyldiazomethyllithium (LiTMSD) with high spin ( = 2) PhB(AdIm)FeCl (PhB(AdIm) = tris(3-adamantylimidazol-2-ylidene)phenylborate) affords the corresponding nitrilimido complex PhB(AdIm)Fe-N═N═C(SiMe). This complex can be converted to the thermodynamically more favorable -isocyanoamido isomer PhB(AdIm)Fe-C═N═N(SiMe) by reaction with an additional equivalent of LiTMSD. While the iron(II) complexes are four-coordinate, the diazomethane is bound side-on in the iron(I) congener PhB(AdIm)Fe(,'-κ-NC(H)Si(CH)). The latter complex adopts high spin ( = 3/2) ground state and features an unusually weak C-H bond. Photolysis of the iron(II) complexes induces N═N bond cleavage, with the iron(II) cyanide PhB(AdIm)Fe-C≡N and iron(IV) nitride PhB(AdIm)Fe≡N complexes being the major products of the reaction. The same products are obtained when the iron(I) complex is photolyzed or treated with a fluoride source. The trimethylsilyldiazomethane-derived ligand disassembly reactions are contrasted with those observed for related tris(carbene)amine complexes.