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碳纤维复合材料的微波热解回收与再利用性能研究

Research on Microwave Pyrolysis Recovery and Reuse Performance of Carbon Fiber Composites.

作者信息

Li Xuan, Xu Lei, Ren Yiyao, Nan Zheng, Xiao Shijie, Shen Zhigang

机构信息

Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China.

State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China.

出版信息

Polymers (Basel). 2024 May 12;16(10):1383. doi: 10.3390/polym16101383.

Abstract

Carbon fiber-reinforced resin matrix composites find extensive applications across various industries. However, their widespread use also generates significant waste, leading to resource depletion and environmental concerns. Studying the production of composite materials using recovered carbon fiber is imperative to mitigate the environmental impact associated with waste from carbon fiber-reinforced resin matrix composites and optimize resource utilization. In this study, carbon fiber was reclaimed using the microwave pyrolysis-oxidation process. The reclaimed carbon fiber underwent a cutting process to produce shorter carbon fibers tailored to specific requirements, which were then used to fabricate composite plates reinforced with epoxy resin. The mechanical characteristics of the composite were analyzed, along with SEM, XPS, infrared, Raman, and contact angle analyses conducted on the recovered carbon fiber. The test findings suggested minimal variation in the surface morphology of the recovered carbon fiber materials. Post-recovery, an increase in the quantity of oxygen-containing functional groups was observed on the carbon fiber surface. Additionally, the contact angle between the carbon fiber surface and the epoxy adhesive decreased. The mechanical properties of the composite produced from the recovered carbon fiber decreased, including the impact strength, tensile strength, and bending strength, with the impact strength dropping by 24.14%, tensile strength by 15.94%, and bending strength by 8.24%, while maintaining overall reusability, thus paving the way for the comprehensive utilization of carbon fiber resources.

摘要

碳纤维增强树脂基复合材料在各个行业有着广泛的应用。然而,它们的广泛使用也产生了大量废弃物,导致资源枯竭和环境问题。研究使用回收碳纤维生产复合材料对于减轻与碳纤维增强树脂基复合材料废弃物相关的环境影响以及优化资源利用至关重要。在本研究中,采用微波热解氧化工艺回收碳纤维。回收的碳纤维经过切割工艺,制成符合特定要求的短碳纤维,然后用于制造环氧树脂增强复合板。分析了复合材料的力学特性,并对回收碳纤维进行了扫描电子显微镜(SEM)、X射线光电子能谱(XPS)、红外、拉曼和接触角分析。测试结果表明,回收碳纤维材料的表面形态变化极小。回收后,观察到碳纤维表面含氧官能团数量增加。此外,碳纤维表面与环氧胶粘剂之间的接触角减小。由回收碳纤维制成的复合材料的力学性能下降,包括冲击强度、拉伸强度和弯曲强度,冲击强度下降24.14%,拉伸强度下降15.94%,弯曲强度下降8.24%,同时保持了整体可重复使用性,从而为碳纤维资源的综合利用铺平了道路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/568a/11126046/aeda2df964c1/polymers-16-01383-g001.jpg

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