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在中试规模的紫外线设备中,使用紫外线照射(254/185纳米)和过硫酸钠降解活性红(B-3BF)染料废水。

Degradation of reactive red (B-3BF) dye wastewater using UV irradiation (254/185 nm) with sodium persulfate in a pilot UV device.

作者信息

Wang Chao, Li Yongqiang, Wan Junmin, Hu Yi, Huang Yi, Qiu Jiangen

机构信息

College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, No. 928, 2nd Street, Xiasha Higher Education Zone, Hangzhou City, 310018, Zhejiang Province, China.

Tongxiang Research Institute, Zhejiang Sci-Tech University, No. 1488, Development Avenue, Tongxiang City, Jiaxing City, 314599, Zhejiang Province, China.

出版信息

Sci Rep. 2024 May 27;14(1):12036. doi: 10.1038/s41598-024-62967-3.

Abstract

Two low-pressure ultraviolet (UV) lamps at 185/254 nm with sodium persulfate in a pilot UV device were utilized for the degradation of reactive red (B-3BF) dye wastewater compared with two UV lamps at 185/185 nm and two UV lamps at 254/254 nm. The degradation performances of UV irradiation (254/185 nm) with sodium persulfate under different degradation times, flow rates, initial pH, initial NaSO concentrations and initial dye concentrations were investigated. The experimental results illustrated that the degradation percentage of B-3BF dye could reduce to 90.42% with the energy consumption of 85.1 kWh/kg and the residual dye concentration of 1.92 mg/L by UV irradiation (254/185 nm) with initial NaSO concentration of 1.5 mmol/L and initial dye concentration of 20 mg/L. In addition, degradation performance of B-3BF dye wastewater by UV irradiation (254/185 nm) with sodium persulfate was more effective than those of UV irradiation (254/254 nm) and UV irradiation (185/185 nm). Therefore UV irradiation (254/185 nm) with sodium persulfate was promising for the degradation of B-3BF dye wastewater.

摘要

在中试紫外线装置中,使用两个185/254纳米的低压紫外线灯并添加过硫酸钠,与两个185/185纳米的紫外线灯和两个254/254纳米的紫外线灯相比,用于降解活性红(B-3BF)染料废水。研究了在不同降解时间、流速、初始pH值、初始过硫酸钠浓度和初始染料浓度下,过硫酸钠存在时紫外线照射(254/185纳米)的降解性能。实验结果表明,当初始过硫酸钠浓度为1.5毫摩尔/升、初始染料浓度为20毫克/升时,通过紫外线照射(254/185纳米),B-3BF染料的降解率可降至90.42%,能耗为85.1千瓦时/千克,残留染料浓度为1.92毫克/升。此外,过硫酸钠存在时紫外线照射(254/185纳米)对B-3BF染料废水的降解性能比紫外线照射(254/254纳米)和紫外线照射(185/185纳米)更有效。因此,过硫酸钠存在时紫外线照射(254/185纳米)在降解B-3BF染料废水方面具有前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6e4a/11130176/903b7ac2919e/41598_2024_62967_Fig1_HTML.jpg

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