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使用先进扫描技术的超薄气体扩散层的制造协议及后处理

Manufacturing protocol and post processing of ultra-thin gas diffusion layer using advanced scanning techniques.

作者信息

Pourrahmani Hossein, Van Herle Jan

机构信息

Group of Energy Materials, École Polytechnique Fédérale de Lausanne, 1951, Sion, Switzerland.

University of California, Irvine, California, 92617, USA.

出版信息

Sci Rep. 2024 Jun 7;14(1):13078. doi: 10.1038/s41598-024-63751-z.

Abstract

The typical commercial size of a Gas Diffusion Layer (GDL) for Proton Exchange Membrane Fuel Cell (PEMFC) application is around 180 μm up to 290 μm. GDL facilitates the diffusion of reactants to the catalyst layers and liquid removal from the membrane to the flow field. In this regard, GDL should be a porous region with conductive materials as thin as possible to reduce the size and the costs. Lowering the thickness of the GDL also results in better performance of the stack since it increases the speed of reactants to reach the catalysts. However, the main obstacle is the formation of ultra-thin porous GDL, which can be also named as standalone microporous layer (MPL). The novelty of this study is the manufacturing process and production of ultra-thin porous GDL with carbon and Polytetrafluoroethylene (PTFE) as the main materials. The produced GDL has the thickness of 28.9 μm, which has been measured using microscope imaging. This novel GDL can be used as the conductive diffusive region inside the PEM fuel cells, Alkaline fuel cells, and the cathode of PEM and Alkaline electrolyzers. Additionally, the novel invention can be considered as a 2D membrane for carbon capture purposes after being functionalized.

摘要

用于质子交换膜燃料电池(PEMFC)的气体扩散层(GDL)的典型商业尺寸在180微米至290微米左右。GDL有助于反应物扩散到催化剂层,并将液体从膜中排至流场。在这方面,GDL应是一个带有尽可能薄的导电材料的多孔区域,以减小尺寸和成本。降低GDL的厚度还会提高电池组的性能,因为这会提高反应物到达催化剂的速度。然而,主要障碍是形成超薄多孔GDL,也可称为独立微孔层(MPL)。本研究的新颖之处在于以碳和聚四氟乙烯(PTFE)为主要材料制造超薄多孔GDL的工艺和生产方法。所生产的GDL厚度为28.9微米,这是通过显微镜成像测量得到的。这种新型GDL可用作PEM燃料电池、碱性燃料电池以及PEM和碱性电解槽阴极内部的导电扩散区域。此外,该新发明在功能化后可被视为用于碳捕获的二维膜。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/70f7/11156907/a587726300aa/41598_2024_63751_Fig1_HTML.jpg

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