Liu Zihan, Chen Zihao, Yang Shuangye, Jia Hong, Wei Jie
College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China.
Beijing Engineering Research Center for the Synthesis and Applications of Waterborne Polymers, Beijing 100029, P. R. China.
Langmuir. 2024 Jun 18;40(24):12767-12777. doi: 10.1021/acs.langmuir.4c01383. Epub 2024 Jun 6.
In this study, we prepared a multicolor structural-fluorescent CdS-PEGDA photonic crystal hydrogel (SFC-CPH) with a dual display mode, which has two different optical states: structural color mode and fluorescent color mode. SFC-CPH displays structural color mode under visible light and fluorescent color mode under ultraviolet light. Initially, monodisperse CdS colloidal particles were synthesized via a hydrothermal method, leading to the self-assembly of a photonic crystal template. The high refractive index of CdS contributes to the photonic crystals' low-angle dependence and vivid structural colors. Then, a variety of fluorescent molecules were doped into poly(ethylene glycol) diacrylate (PEGDA) hydrogel and combined with photonic crystals with distinct structural colors to prepare three distinct colors of SFC-CPH. We also investigated the optical characteristics and surface properties of these photonic crystal hydrogels. Based on these dual-mode display characteristics, we designed several dual-mode display patterns and a method for information encoding. The unique property of this photonic crystal hydrogel material suggests its substantial potential for applications in information storage, security, and encoding, offering innovative avenues in the realm of information display.
在本研究中,我们制备了一种具有双显示模式的多色结构荧光硫化镉-聚乙二醇二丙烯酸酯光子晶体水凝胶(SFC-CPH),其具有两种不同的光学状态:结构色模式和荧光色模式。SFC-CPH在可见光下呈现结构色模式,在紫外光下呈现荧光色模式。首先,通过水热法合成单分散硫化镉胶体颗粒,从而实现光子晶体模板的自组装。硫化镉的高折射率有助于光子晶体的低角度依赖性和鲜艳的结构色。然后,将多种荧光分子掺杂到聚乙二醇二丙烯酸酯(PEGDA)水凝胶中,并与具有不同结构色的光子晶体相结合,制备出三种不同颜色的SFC-CPH。我们还研究了这些光子晶体水凝胶的光学特性和表面性质。基于这些双模显示特性,我们设计了几种双模显示图案和一种信息编码方法。这种光子晶体水凝胶材料的独特性质表明其在信息存储、安全和编码方面具有巨大的应用潜力,为信息显示领域提供了创新途径。