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2,9-二氨基-5,6,11,12-四氢二苯并[,]环辛烯的合成与晶体结构

Synthesis and crystal structure of 2,9-di-amino-5,6,11,12-tetra-hydro-dibenzo[,]cyclo-octene.

作者信息

Valdez Nichole, Nagel Eric, Redline Erica, Rodriguez Mark, Staiger Chad, Dugger Jason, Foster Jeffrey

机构信息

Sandia National Laboratories, 1515 Eubank Blvd. SE, Albuquerque, NM 87123, USA.

Oak Ridge National Laboratory, 5200 1 Bethel Valley Rd., Oak Ridge, Tennessee 37831, USA.

出版信息

Acta Crystallogr E Crystallogr Commun. 2024 May 21;80(Pt 6):645-648. doi: 10.1107/S2056989024004468. eCollection 2024 May 1.

DOI:10.1107/S2056989024004468
PMID:38845703
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11151320/
Abstract

The - form of di-amino-dibenzo-cyclo-octane (DADBCO, CHN) is of inter-est as a negative coefficient of thermal expansion (CTE) material. The crystal structure was determined through single-crystal X-ray diffraction at 100 K and is presented herein.

摘要

二氨基二苯并环辛烷（DADBCO，C₁₂H₁₂N₂）的 - 形式作为一种具有负热膨胀系数（CTE）的材料备受关注。其晶体结构是通过在100 K下的单晶X射线衍射确定的，并在此呈现。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea6e/11151320/1b49ba879c84/e-80-00645-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea6e/11151320/cc60e3d969f3/e-80-00645-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea6e/11151320/1b49ba879c84/e-80-00645-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea6e/11151320/cc60e3d969f3/e-80-00645-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea6e/11151320/1b49ba879c84/e-80-00645-fig2.jpg

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