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高氯酸（5-氟-2,6-二氧代-1,2,3,6-四氢嘧啶-1-亚氨基-κ）（1,4,8,11-四氮杂环十四烷-κ）锌（II）

(5-Fluoro-2,6-dioxo-1,2,3,6-tetra-hydro-pyrimidin-1-ido-κ )(1,4,8,11-tetra-aza-cyclo-tetra-decane-κ )zinc(II) perchlorate.

作者信息

Ichimaru Yoshimi, Kato Koichi, Jin Wanchun, Kurihara Masaaki, Kurosaki Hiromasa

机构信息

Faculty of Pharmaceutical Sciences, Shonan University of Medical Sciences, 16-48, Kamishinano, Totsuka-ku, Yokohama, Kanagawa 244-0806, Japan.

College of Pharmacy, Kinjo Gakuin University, 2-1723 Omori, Nagoya 463-8521, Japan.

出版信息

IUCrdata. 2024 May 21;9(Pt 5):x240431. doi: 10.1107/S2414314624004310. eCollection 2024 May.

DOI:10.1107/S2414314624004310
PMID:38846558
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11151294/
Abstract

In the structure of the title complex, [Zn(CHFNO)(CHN)]ClO, the zinc(II) ion forms coordination bonds with the four nitro-gen atoms of cyclam (1,4,8,11-tetra-aza-cyclo-tetra-decane or [14]aneN4) as well as with the nitro-gen atom of a deprotonated 5-fluoro-uracil ion (FU). Cyclam adopts a -I type conformation within this structure. The coordination structure of the zinc(II) ion is a square pyramid with a distorted base plane formed by the four nitro-gen atoms of the cyclam. FU engages in inter-molecular hydrogen bonding with neighboring FU mol-ecules and with the cyclam mol-ecule.

摘要

在标题配合物[Zn(CHFNO)(CHN)]ClO的结构中，锌(II)离子与环胺（1,4,8,11-四氮杂环十四烷或[14]aneN4）的四个氮原子以及去质子化的5-氟尿嘧啶离子（FU）的氮原子形成配位键。环胺在该结构中呈-I型构象。锌(II)离子的配位结构是一个方锥，其底面由环胺的四个氮原子形成的平面发生扭曲。FU与相邻的FU分子以及环胺分子之间存在分子间氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/edbb/11151294/3a8902469bd9/x-09-x240431-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/edbb/11151294/6cca81e2bc4b/x-09-x240431-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/edbb/11151294/fe39660a7288/x-09-x240431-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/edbb/11151294/f14b16727d09/x-09-x240431-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/edbb/11151294/3a8902469bd9/x-09-x240431-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/edbb/11151294/6cca81e2bc4b/x-09-x240431-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/edbb/11151294/fe39660a7288/x-09-x240431-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/edbb/11151294/f14b16727d09/x-09-x240431-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/edbb/11151294/3a8902469bd9/x-09-x240431-fig4.jpg

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