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一种分层的CoS/Ni(OH)异质结构作为用于尿素辅助高效制氢的双功能电催化剂。

A hierarchical CoS/Ni(OH) heterostructure as a bifunctional electrocatalyst for urea-assisted energy-efficient hydrogen production.

作者信息

Sang Bin, Xue Chaozhuang, Guo Songyun, Wng Xiaojun, Xie Shuixiang, Wang Changming, Li Rui-Qing

机构信息

School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, China.

School of Textile and Clothing, Nantong University, Nantong 226019, China.

出版信息

Chem Commun (Camb). 2024 Jun 25;60(52):6643-6646. doi: 10.1039/d4cc01253d.

DOI:10.1039/d4cc01253d
PMID:38855908
Abstract

We report hierarchical CoS/Ni(OH)/NF heterostructure nanorod arrays, which manifest superior bifunctional catalytic activities for the HER and UOR due to amorphous Ni(OH), synergistic effect of multiple components and self-supported structure. The CoS/Ni(OH)/NF-based urea electrolyzer requires a low cell voltage of 1.485 V to deliver 10 mA cm, which is obviously lower than that needed in water electrolysis.

摘要

我们报道了分层的CoS/Ni(OH)/NF异质结构纳米棒阵列,由于非晶态Ni(OH)、多组分的协同效应和自支撑结构,该阵列对析氢反应(HER)和尿素氧化反应(UOR)表现出优异的双功能催化活性。基于CoS/Ni(OH)/NF的尿素电解槽在提供10 mA cm电流时需要1.485 V的低电池电压,这明显低于水电解所需的电压。

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