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四苯基取代三苯胺衍生物的多重刺激响应双聚集诱导发光和光致变色行为及其作为防伪剂的应用

Multi Stimuli Responsive Dual Aggregation-Induced Emission and Photochromic Behavior of a Tetraphenyl Substituted Triphenylamine Derivative and its Application as Anti-counterfeiting Agent.

作者信息

Bokotial Dikshit, Bhattacharyya Soumalya, Arunkumar S, Das Trisha, Mini Rajendran Gokul Raj, Chowdhury Aniket

机构信息

Department of Industrial Chemistry, Mizoram University, Aizawl, 796004, India.

Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore, 560012, India.

出版信息

Chemistry. 2024 Aug 27;30(48):e202402086. doi: 10.1002/chem.202402086. Epub 2024 Jul 30.

Abstract

A multi-stimuli responsive tetraphenyl substituted tripehnylamine-based aggregation induced emissive (AIE) material coupled with spiropyran was prepared. Owing to the presence of AIE and photochromic moiety, the molecule exhibits emissive aggregates, photochromism, and acidochromism. The multiple stimuli sensitive behavior of the molecule was explored for anti-counterfeiting behavior on TLC plate and commercial banknotes. The fluorogenic and photogenic response under UV and visible light established the potential of the candidate as a new generation encryption material.

摘要

制备了一种基于四苯基取代三苯胺的多刺激响应聚集诱导发光(AIE)材料,其与螺吡喃偶联。由于存在AIE和光致变色部分,该分子表现出发射性聚集体、光致变色和酸致变色特性。探索了该分子的多重刺激敏感行为在薄层色谱板和商业纸币上的防伪应用。该材料在紫外光和可见光下的荧光和光致发光响应表明其有潜力成为新一代加密材料。

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