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用蝴蝶豆花花色苷和银纳米粒子修饰的马铃薯氧化羟丙基淀粉/果胶基指示剂薄膜用于监测冷藏牛肉的新鲜度。

Potato oxidized hydroxypropyl starch/pectin-based indicator film with Clitoria ternatea anthocyanin and silver nanoparticles for monitoring chilled beef freshness.

机构信息

College of Food Science and Engineering, Gansu Agricultural University, Lanzhou, China.

College of Food Science and Engineering, Gansu Agricultural University, Lanzhou, China.

出版信息

Int J Biol Macromol. 2024 Jul;273(Pt 2):133106. doi: 10.1016/j.ijbiomac.2024.133106. Epub 2024 Jun 13.

DOI:10.1016/j.ijbiomac.2024.133106
PMID:38876228
Abstract

Potato oxidized hydroxypropyl starch (POHS)/pectin (P) functional and smart beef freshness indicator films were prepared using butterfly pea (Clitoria ternatea) anthocyanin (BA) and silver nanoparticles (AgNPs). BA exhibited significant pH-responsive color changes. BA and AgNPs were evenly distributed within a polymer matrix to create a compatible film with POHS/P. The films containing BA and AgNPs had good UV resistance and maintained strong mechanical strength, barrier properties, and color stability. The color of the indicator film changed from purple to green when exposed to ammonia, with the 1 % POHS/P/BA/AgNPs film showing the most sensitive response. The films also demonstrated strong antibacterial and antioxidant properties. The freshness of beef was monitored using 1 % POHS/P/BA/AgNPs films and was identified as sub-fresh and spoiled on days 4 and 7, respectively. The relationship between the color change of the indicator label and the freshness of chilled beef was established: purple for fresh meat, blue for less fresh meat, and green for spoiled meat. Thus, the new POHS/P/BA/AgNPs film can serve as a smart packaging material to indicate food freshness and extend shelf life. These results suggest that POHS/P/BA/AgNPs films have significant potential as an active and smart food packaging material.

摘要

采用蝶豆花(Clitoria ternatea)花色苷(BA)和银纳米粒子(AgNPs)制备了马铃薯氧化羟丙基淀粉(POHS)/果胶(P)功能型和智能牛肉新鲜度指示薄膜。BA 表现出显著的 pH 响应颜色变化。BA 和 AgNPs 均匀分布在聚合物基质中,以与 POHS/P 形成相容性薄膜。含有 BA 和 AgNPs 的薄膜具有良好的耐 UV 性,并保持较强的机械强度、阻隔性能和颜色稳定性。当暴露于氨时,指示薄膜的颜色从紫色变为绿色,其中 1% POHS/P/BA/AgNPs 薄膜表现出最敏感的响应。这些薄膜还表现出较强的抗菌和抗氧化性能。使用 1% POHS/P/BA/AgNPs 薄膜监测牛肉的新鲜度,并分别在第 4 天和第 7 天确定为亚新鲜和变质。建立了指示标签颜色变化与冷藏牛肉新鲜度之间的关系:紫色表示新鲜肉,蓝色表示不太新鲜的肉,绿色表示变质的肉。因此,新型 POHS/P/BA/AgNPs 薄膜可用作指示食物新鲜度和延长保质期的智能包装材料。这些结果表明,POHS/P/BA/AgNPs 薄膜作为一种活性和智能食品包装材料具有很大的潜力。

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