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TiO/PPy 纳米复合材料在光催化应用中的研究:合成、表征及与各种基底的结合:综述。

Investigation of TiO/PPy nanocomposite for photocatalytic applications; synthesis, characterization, and combination with various substrates: a review.

机构信息

Chemical Engineering Department, Engineering Faculty, University of Guilan, Rasht, 41996-13776, Iran.

Hybrid Nanomaterials & Environment Lab, Fouman Faculty of Engineering, College of Engineering, University of Tehran, Fouman, 43581-39115, Iran.

出版信息

Environ Sci Pollut Res Int. 2024 Jun;31(30):42521-42546. doi: 10.1007/s11356-024-33893-8. Epub 2024 Jun 15.

Abstract

The use of photocatalysis technology, specifically visible light photocatalysis that relies on sustainable solar energy, is the most promising for the degradation of contaminants. The interaction of conducting polymer and titanium dioxide (TiO) leads to the exchange that enhances the alteration of the semiconductor's surface and subsequently decreases the bandgap energy. Polypyrrole (PPy) and TiO nanocomposites have promising potential for photocatalytic degradation. Chemically and electrochemical polymerization are two predominant methods for adding inorganic nanoparticles to a conducting polymer host matrix. The most commonly utilized method for producing PPy/TiO nanocomposites is the in-situ chemical oxidative polymerization technique. Immobilizing PPy/TiO on substrates causes more charge carriers (electron/hole pairs) to be produced on the surface of TiO and enhances the rate of photocatalytic degradation compared to pure TiO. The increased surface charge affects how electron/hole pairs are formed when visible light is used. This study provides a comprehensive investigation into the synthesis, characterization, application, efficiency, and mechanism of PPy/TiO nanocomposites in the photocatalytic degradation process of various pollutants. Furthermore, the effect of stabilizing the TiO/PPy nanocomposite on various substrates will be investigated. In conclusion, the review outlines the ongoing challenges in utilizing these photocatalysts and highlights the essential concerns that require attention in future research. Its objective is to help researchers better understand photocatalysts and encourage their use in wastewater treatment.

摘要

光催化技术的应用,特别是利用可持续太阳能的可见光光催化,是降解污染物最有前途的方法。导电聚合物和二氧化钛(TiO)的相互作用导致了电子的交换,增强了半导体表面的改变,并随后降低了带隙能量。聚吡咯(PPy)和 TiO 纳米复合材料在光催化降解方面具有很大的潜力。化学和电化学聚合是将无机纳米粒子添加到导电聚合物主基质中的两种主要方法。最常用的制备 PPy/TiO 纳米复合材料的方法是原位化学氧化聚合技术。将 PPy/TiO 固定在基质上会导致 TiO 表面产生更多的载流子(电子/空穴对),并提高光催化降解的速率,与纯 TiO 相比。增加的表面电荷会影响可见光使用时电子/空穴对的形成方式。本研究全面调查了 PPy/TiO 纳米复合材料在各种污染物的光催化降解过程中的合成、表征、应用、效率和机制。此外,还将研究在各种基底上稳定 TiO/PPy 纳米复合材料的效果。总之,综述概述了利用这些光催化剂所面临的挑战,并强调了未来研究中需要关注的关键问题。其目的是帮助研究人员更好地理解光催化剂,并鼓励它们在废水处理中的应用。

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